Han Bai, Chang Jiaxin, Song Wei, Sun Zhi, Yin Chuqi, Lv Penghao, Wang Xuan
Key Laboratory of Engineering Dielectrics and Its Application, Ministry of Education, Harbin University of Science and Technology, Harbin 150080, Heilongjiang, China.
State Key Laboratory Breeding Base of Dielectrics Engineering, Harbin University of Science and Technology, Harbin 150080, Heilongjiang, China.
Polymers (Basel). 2019 Dec 9;11(12):2035. doi: 10.3390/polym11122035.
The interface area of nano-dielectric is generally considered to play an important role in improving dielectric properties, especially in suppressing space charge. In order to study the role of interface area on a microscopic scale, the natural charge and injected charge movement and diffusion on the surface of pure LDPE and SiO/LDPE nanocomposite were observed and studied by gradual discharge under electrostatic force microscope (EFM). It was detected that the charge in SiO/LDPE nanocomposite moved towards the interface area and was captured, which indicates that the charge was trapped in the interface area and formed a barrier to the further injection of charge and improving the dielectric performance as a result. Moreover, pulsed electro-acoustic (PEA) short-circuited test after charge injection was carried out, and the change of total charge was calculated. The trend of charge decay in the EFM test is also generally consistent with that in PEA short-circuit test and can be used to verify one another. The results revealed the law of charge movement and verified the interface area can inhibit space charge injection in nano-dielectric at the microscale, which provides an experimental reference for relevant theoretical research.
纳米电介质的界面面积通常被认为在改善介电性能方面起着重要作用,特别是在抑制空间电荷方面。为了在微观尺度上研究界面面积的作用,通过静电力显微镜(EFM)下的逐步放电,观察并研究了纯LDPE和SiO/LDPE纳米复合材料表面的自然电荷以及注入电荷的移动和扩散。检测到SiO/LDPE纳米复合材料中的电荷向界面区域移动并被捕获,这表明电荷被困在界面区域,从而形成了对电荷进一步注入的阻挡,并因此改善了介电性能。此外,在电荷注入后进行了脉冲电声(PEA)短路测试,并计算了总电荷的变化。EFM测试中的电荷衰减趋势与PEA短路测试中的趋势也基本一致,并且可以相互验证。结果揭示了电荷移动规律,并验证了界面面积在微观尺度上可以抑制纳米电介质中的空间电荷注入,这为相关理论研究提供了实验参考。