CEB- Centre of Biological Engineering, Universidade do Minho, Campus de Gualtar, 4710-057 Braga, Portugal.
LEPABE - Laboratory for Process Engineering, Environment, Biotechnology and Energy, Faculdade de Engenharia da Universidade do Porto, Rua Dr. Roberto Frias, 4200-465 Porto, Portugal.
Carbohydr Polym. 2020 Feb 15;230:115657. doi: 10.1016/j.carbpol.2019.115657. Epub 2019 Nov 22.
Bacterial cellulose (BC) is an emerging alternative to plant cellulose in different applications. Several works demonstrated the potential of never-dried BC; however, envisioning real industrial applications, a dry product retaining its functional properties upon rehydration is preferable. A dry and completely redispersible formulation of BC with carboxymethyl cellulose (CMC) was prepared by Spray-drying. The obtained material showed a Zeta Potential of (-67.0 ± 3.9) mV, a Dv(50) of (601 ± 19.7) μm and was able to decrease the oil/water interface energy. The dry BC:CMC formulation was employed as a stabilizer in oil-in-water emulsions, in parallel with commercial plant celluloses and Xanthan gum. The emulsions were monitored over time by optical microscopy and characterized by rheological measurements. BC:CMC effectively stabilized emulsions against coalescence and creaming, at a concentration of 0.50 % - contrarily to other commercial dry celluloses - due to the Pickering effect and to the structuring of the continuous phase, as seen with Cryo-SEM.
细菌纤维素(BC)是一种在不同应用中替代植物纤维素的新兴材料。有几项研究表明了从未干燥的 BC 的潜力;然而,为了设想真正的工业应用,干燥产品在重新水合后保留其功能特性是更好的。通过喷雾干燥制备了具有羧甲基纤维素(CMC)的干燥且完全可再分散的 BC 配方。所得到的材料的 Zeta 电位为 (-67.0 ± 3.9) mV,Dv(50)为 (601 ± 19.7) μm,并且能够降低油/水界面能。干燥的 BC:CMC 配方被用作水包油乳液中的稳定剂,与商业植物纤维素和黄原胶平行使用。通过光学显微镜监测乳液随时间的变化,并通过流变测量进行表征。BC:CMC 有效地稳定了乳液,防止了聚结和乳析,浓度为 0.50% - 与其他商业干燥纤维素不同 - 这是由于 Pickering 效应和连续相的结构化,如冷冻扫描电子显微镜所见。