Two Ni/Co-substituted sandwich-type germanomolybdates based on an unprecedented trivacant polyanion [α-GeMoO].
作者信息
Xu Hui, Liu Xing-Man, Su Tan, Chen Wei-Chao, Su Zhong-Min
机构信息
College of Chemistry, Jilin University, Changchun 130012, PR China.
Department of Chemistry, Northeast Normal University, Changchun 130024, PR China.
出版信息
Dalton Trans. 2020 Jan 28;49(4):977-982. doi: 10.1039/c9dt04433g. Epub 2020 Jan 6.
Two Ni/Co-substituted sandwich-type germanomolybdates, {[M(NH-trz)(HO)][M(HO)(HGeMoO)]}·nHO (M = Ni (1) and Co (2), n = 10 (1) or 11 (2), NH-trz = 4-amino-1,2,4-triazole), have been obtained under hydrothermal conditions. 1 and 2 represent the first trivacant Keggin germanomolybdates involving unprecedented [α-GeMoO] fragments and {MO} quasi-cubane building units. Both of them exhibit electrocatalytic behaviours for HO reduction and photocatalytic properties for CO conversion.
Zotero 插件