Badawy Wael M, Duliu Octavian G, Frontasyeva Marina V, El-Samman Hussien, Mamikhin Sergey V
Egyptian Atomic Energy Authority (EAEA), Nuclear Research Center, Radiation Protection & Civil Defense Dept, 13759, Abu Zaabal, Egypt.
Frank Laboratory of Neutron Physics, Joint Institute for Nuclear Research, 6, Joliot Curie Str. 141980, Dubna, Russian Federation.
Data Brief. 2019 Dec 24;28:105009. doi: 10.1016/j.dib.2019.105009. eCollection 2020 Feb.
This data is the first comprehensive baseline data on the geochemical composition of soil and sediments along the Nile River and Delta in Egypt that was subjected and analyzed by instrumental neutron activation analysis INAA. These data supported the research articles that were done to evaluate the elemental compositions and pollution sources in 176 sampling locations through 133 soil and 43 sediments samples along the Egyptian section of the Nile River and Delta - Egypt. "Geochemistry of sediments and surface soils from the Nile delta and lower Nile valley studied by epithermal neutron activation analysis" Arafa [1], "Major and trace element distribution in soil and sediments from the Egyptian central Nile valley" Badawy [2], and "Assessment of industrial contamination of agricultural soil adjacent to Sadat city, Egypt" Badawy [3]. The samples were analyzed by means of instrumental neutron activation analysis INAA and the concentrations in mg/kg of 28 major and trace elements are obtained. The quality control of the analytical measurements was carried out using different certified reference materials. Multivariate statistical analyses were applied. A total of eight individual and complex pollution indices were calculated in terms of the quantification of pollution extent and selection of the proper index based on the method and purpose of calculations. The spatial distribution of pollution load index PLI was mapped using GIS-technology. The normalized concentrations of the determined elements show no significant difference between soil and sediments concentrations and this, however, may be explained by the fact that origin of soil mainly is the sediments. To a clear extent, the concentrations of Ti (8017, 9672 mg/kg), V (124, 143 mg/kg), Cr (126, 160 mg/kg), and Zr (296, 318 mg/kg) are observed to be high in soil and sediments, respectively relative to other elements. Zr/Sc ratio shows a reduced sedimentary recycling and this may be explained by the tremendous influence of Aswan High Dam in preventing sediments supply from Ethiopian Highlights. Eventually, the pollution indices prove their suitability for assessing the individual and integrative contamination and show that there is no overall contamination. However, there are some contaminated localities mainly in Delta and mostly due to the dense population and anthropogenic activities. The data can be used as a raw data for constructing the first ecological atlas and evaluation of the ecological situation in terms of geochemistry and pollution.
这些数据是关于埃及尼罗河及其三角洲沿岸土壤和沉积物地球化学组成的首批全面基线数据,采用仪器中子活化分析(INAA)对其进行了分析。这些数据为相关研究文章提供了支持,这些文章通过对尼罗河埃及段和三角洲地区133个土壤样本和43个沉积物样本的176个采样点进行分析,评估了元素组成和污染源。如阿拉法的《用超热中子活化分析法研究尼罗河三角洲和尼罗河谷下游沉积物及表层土壤的地球化学》[1]、巴达维的《埃及尼罗河中游土壤和沉积物中的主要和微量元素分布》[2]以及巴达维的《埃及萨达特市附近农业土壤的工业污染评估》[3]。通过仪器中子活化分析(INAA)对样本进行分析,得出了以mg/kg为单位的28种主要和微量元素的浓度。使用不同的标准参考物质进行分析测量的质量控制。应用了多元统计分析。根据污染程度的量化以及基于计算方法和目的选择合适的指标,共计算了八个单独和综合的污染指数。利用地理信息系统(GIS)技术绘制了污染负荷指数(PLI)的空间分布图。所测元素的归一化浓度表明土壤和沉积物浓度之间无显著差异,然而,这可能是由于土壤主要来源于沉积物这一事实所致。在一定程度上,相对于其他元素,土壤中Ti(8017、9672mg/kg)、V(124、143mg/kg)、Cr(126、160mg/kg)以及沉积物中Zr(296、318mg/kg)的浓度较高。Zr/Sc比值表明沉积循环减少,这可能是由于阿斯旺大坝对阻止埃塞俄比亚高地的沉积物供应产生了巨大影响。最终,污染指数证明了它们在评估个体和综合污染方面的适用性,并表明不存在整体污染。然而,存在一些受污染地区,主要在三角洲,且大多是由于人口密集和人为活动造成的。这些数据可作为构建首个生态地图集以及从地球化学和污染角度评估生态状况的原始数据。