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烟气中氮氧化物减排技术:综述。

Technologies for the nitrogen oxides reduction from flue gas: A review.

机构信息

New Technologies - Research Centre, Engineering of Special Materials, University of West Bohemia, Plzeň 301 00, Czech Republic.

New Technologies - Research Centre, Engineering of Special Materials, University of West Bohemia, Plzeň 301 00, Czech Republic.

出版信息

Sci Total Environ. 2020 Apr 20;714:136712. doi: 10.1016/j.scitotenv.2020.136712. Epub 2020 Jan 15.

Abstract

The required energy of the global industry is mostly generated from fossil fuel sources, such as natural gas, gasoline, diesel, oil, and coal. Nitrogen oxides are one of the main air pollutants that are produced from the combustion of fossil fuels in stationary and mobile sources. Development of new technologies to decrease the NO emission from exhaust gases is essential due to the harmful effect of NO on the environment and human health. Compared with pre-combustion and combustion methods (with <50% NO removal efficiency), the post-combustion methods with higher efficiency (above 80%) have attracted more attention in NO elimination. This review describes the currently used technologies of NO abatement. Different available post-combustion methods of NO removal, including selective catalytic reduction (using different types of reducing reagents, including ammonia, hydrogen, hydrocarbons, and carbon monoxide), selective noncatalytic reduction, wet scrubbing, adsorption, electron beam, nonthermal plasma, and electrochemical reduction of NO, are discussed.

摘要

全球工业所需的能源主要来自化石燃料,如天然气、汽油、柴油、石油和煤炭。氮氧化物是主要的空气污染物之一,它是由固定源和移动源燃烧化石燃料产生的。由于 NO 对环境和人体健康的有害影响,开发新的技术来减少废气中的 NO 排放是至关重要的。与预燃烧和燃烧方法(NO 去除效率<50%)相比,具有更高效率(超过 80%)的后燃烧方法在 NO 消除方面引起了更多关注。本文综述了目前用于减少 NO 的技术。讨论了不同可用的后燃烧 NO 去除方法,包括选择性催化还原(使用不同类型的还原剂,包括氨、氢、碳氢化合物和一氧化碳)、选择性非催化还原、湿法洗涤、吸附、电子束、非热等离子体和电化学还原 NO。

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