Hollow 3D Frame Structure Modified with NiCo S Nanosheets and Spinous Fe O Nanowires as Electrode Materials for High-Performance All-Solid-State Asymmetric Supercapacitors.

Supercapacitors have attracted tremendous research interest, since they are expected to achieve battery-level energy density, while having a long calendar life and short charging time. Herein, a novel asymmetric supercapacitor has been successfully assembled from NiCo S nanosheets and spinous Fe O nanowire modified hollow melamine foam decorated with polypyrrole as positive and negative electrodes, respectively. Owing to the well-designed nanostructure and suitable matching of electrode materials, the assembled asymmetric supercapacitor (ASC) exhibits an extended operation voltage window of 1.6 V with an energy density of 20.1 Wh kg at a power density of 159.4 kW kg . Moreover, the ASC shows stable cycling stability, with 81.3 % retention after 4000 cycles and a low internal resistance of 1.03 Ω. Additionally, a 2.5 V light-emitting diode indicator can be lit up by three ASCs connected in series; this provides evidence of the practical application potential of the assembled energy-storage system. The excellent electrochemical performances should be credited to the significant enhancement of the specific surface area, charge transport, and mechanical stability resulting from the unique 3D morphology.