Key Laboratory of Jiangsu Province for Chemical Pollution Control and Resources Reuse, School of Environmental and Biological Engineering, Nanjing University of Science and Technology, Nanjing, 210094, China.
School of Environmental Science and Engineering, Nanjing Tech University, Nanjing, China.
Chemosphere. 2020 Jun;248:126028. doi: 10.1016/j.chemosphere.2020.126028. Epub 2020 Jan 27.
As increasing demand of global reuse water, microbial desalination cell (MDC) is developed as a potential desalination approach to drive ion migration and separation through biodegradation without any additional energy. A novel, efficient, stable reactor coupled stacked MDC with upflow MDC was constructed, which was named as upflow-stacked MDC (USMDC). Compared with the traditional stacked MDC and upflow MDC, the desalination and generation performance of the USMDC was evaluated. Results showed that, after 24 h, the desalination ratio of USMDC can reach 91.9% when the external resistance was 1.5 Ω, which was 1.18 and 1.48 times higher than SMDC and UMDC, respectively. The long-term performance of the desalination efficiency was tested, which was maintained at 87.2-96.0% and stable for consecutive 120 days. Then, it was also the investigated that the relationship between desalination rate and external resistance during every period. The USMDC produced a maximum power density of 32.91 W m. In addition, the difference of current density between USMDC and SMDC indicates the turbulence generated by cylindrical structure could effectively decrease the internal resistance. It was also corroborated that salt concentration gradient and bipolar electrodialysis would decline the charge transfer efficiency. Accordingly, USMDC was verified having the superior desalination performance thus providing the possibility for application in wastewater reuse.
随着全球对再生水需求的不断增加,微生物脱盐电池 (MDC) 作为一种有潜力的脱盐方法得到了发展,它可以通过生物降解在无需额外能源的情况下驱动离子迁移和分离。本文构建了一种新型、高效、稳定的堆叠式微生物脱盐电池与上流式微生物脱盐电池耦合的反应器,命名为上流式堆叠微生物脱盐电池(USMDC)。与传统的堆叠式微生物脱盐电池和上流式微生物脱盐电池相比,评估了 USMDC 的脱盐和发电性能。结果表明,在外阻为 1.5 Ω 时,USMDC 在 24 h 后脱盐率可达到 91.9%,分别是 SMDC 和 UMDC 的 1.18 倍和 1.48 倍。对脱盐效率的长期性能进行了测试,连续 120 天内保持在 87.2-96.0%,稳定性能良好。然后,还研究了每个阶段脱盐率与外阻之间的关系。USMDC 的最大功率密度为 32.91 W/m。此外,USMDC 和 SMDC 之间的电流密度差异表明圆柱结构产生的湍流可以有效降低内阻。还证实了盐浓度梯度和双极电渗析会降低电荷转移效率。因此,USMDC 具有优越的脱盐性能,从而为废水再利用的应用提供了可能性。