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将 MDF 废料转化为具有显著去除水污染物中食品红 17 染料潜力的炭。

Conversion of MDF wastes into a char with remarkable potential to remove Food Red 17 dye from aqueous effluents.

机构信息

Chemical Engineering Department, Federal University of Santa Maria, UFSM, Roraima Avenue, 1000, 97105-900, Santa Maria, RS, Brazil.

Postgraduate Program in Engineering Processes and Technology, University of Caxias do Sul - UCS, Caxias do Sul, RS, Brazil.

出版信息

Chemosphere. 2020 Jul;250:126248. doi: 10.1016/j.chemosphere.2020.126248. Epub 2020 Feb 17.

Abstract

Medium density fiberboard (MDF) wastes were converted into an efficient char able to uptake Food Red 17 dye (FR17) from colored effluents. The yield of the pyrolysis process, in terms of char, was 29%. The produced char presented micro and mesoporous, with surface area of 218.8 m g and total pore volume of 0.122 cm g. Regarding to the FR17 adsorption, removal percentages of 90% were found at pH 2 and using 0.5 g L of char. Pseudo-first and pseudo-second order models were adequate to represent the adsorption kinetic profile, being the equilibrium reached within 20 min. Freundlich model was selected to represent the equilibrium data. The maximum adsorption capacity was 210 mg g. The adsorption of FR17 on the char was endothermic and physical in nature. The char was efficient for 8 adsorption-desorption cycles, maintaining the same adsorption capacity. In brief, this work demonstrated a useful practice in terms of cleaner production. It was possible add value to MDF wastes, generating an efficient and reusable adsorbent to treat colored effluents containing FR 17 dye.

摘要

中密度纤维板 (MDF) 废料转化为一种高效的炭,能够从有色废水中吸附食用红 17 染料 (FR17)。热解过程以炭的形式生成的产率为 29%。所制备的炭具有微孔和介孔结构,比表面积为 218.8 m²/g,总孔体积为 0.122 cm³/g。在 pH 值为 2 且使用 0.5 g/L 炭的条件下,发现 FR17 的去除率达到 90%。拟一级和拟二级模型均适合表示吸附动力学曲线,平衡在 20 分钟内达到。选择 Freundlich 模型来表示平衡数据。最大吸附容量为 210 mg/g。FR17 在炭上的吸附是吸热和物理性质的。该炭在 8 次吸附-解吸循环中有效,保持相同的吸附容量。总之,这项工作在清洁生产方面展示了一种有用的实践。可以对 MDF 废料进行增值利用,生成高效且可重复使用的吸附剂来处理含有 FR17 染料的有色废水。

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