Three-Dimensional and In Situ-Activated Spinel Oxide Nanoporous Clusters Derived from Stainless Steel for Efficient and Durable Water Oxidation.

Developing cost-effective and highly efficient oxygen evolution reaction (OER) electrocatalysts based on earth-abundant elements is vital to hydrogen production from electrocatalytic water splitting. Herein, a three-dimensional and in situ-activated electrocatalyst derived from stainless steel is successfully fabricated via a two-step laser direct writing strategy. The electrocatalyst appears in the form of nanoparticle-stacked porous clusters on the multiscale stainless steel with irregular microcone arrays and microspheres, which exposes more active sites and facilitates the mass transport. Especially, the clusters undergoe a self-optimizing morphological and compositional reconfiguration induced by the leaching of Cr species under OER conditions for favorable charge transfer and enhanced intrinsic catalytic activity. As a result, the in situ-activated, Ni/Cr-doped FeO electrocatalyst exhibits an outstanding OER performance with a small overpotential of 262 mV to reach 10 mA cm, a low Tafel slope of 35.0 mV dec, and excellent long-term stability of 120 h, among the best spinel Fe-rich OER electrocatalysts. Finally, we also verify the feasibility of the affordable and efficient electrocatalyst coupled with the commercial Ni cathode in the practical water electrolysis. This work may open up a new avenue to design nanostructured metal oxides for various energy applications and beyond.