Department of Applied Chemistry, National Chiao Tung University, Hsinchu, 30010, Taiwan.
Graduate School of Materials Science, Nara Institute of Science and Technology, Ikoma, Nara, 630-0192, Japan.
Macromol Rapid Commun. 2020 Apr;41(8):e2000035. doi: 10.1002/marc.202000035. Epub 2020 Mar 3.
1D polymer nanomaterials have attracted significant interest in recent years because of their unique properties and promising applications in various fields. It is, however, still a challenge to fabricate polymer nanoarrays with desired sizes and controlled morphologies. Here, an unprecedented approach, the laser-assisted nanowetting (LAN) method, to selectively fabricate polymer nanoarrays is presented. Polystyrene (PS) is blended with gold nanorods (AuNRs), which are used to absorb the energy from the laser. After the blend films are brought in contact with AAO templates, the AuNRs at regions shone by the laser beams absorb the energy and heat the surrounding polymer chains, resulting in the formation of PS/AuNRs arrays in selected areas. This work paves a new research direction for developing template-based polymer nanomaterials.
1D 聚合物纳米材料因其独特的性质和在各个领域的广阔应用前景而引起了广泛关注。然而,制备具有所需尺寸和可控形态的聚合物纳米阵列仍然是一个挑战。在这里,我们提出了一种前所未有的方法,即激光辅助纳米浸润(LAN)方法,用于选择性地制备聚合物纳米阵列。聚苯乙烯(PS)与金纳米棒(AuNRs)混合,AuNRs 用于吸收激光能量。将混合膜与 AAO 模板接触后,激光照射区域的 AuNRs 吸收能量并加热周围的聚合物链,从而在选定区域形成 PS/AuNRs 阵列。这项工作为开发基于模板的聚合物纳米材料开辟了新的研究方向。