Synthesis and Characterization of Two New Second Harmonic Generation Active Iodates: KSc(IO) and KSc(IO)Cl.

Transparent single crystals of two new iodates KSc(IO) and KSc(IO)Cl have been synthesized hydrothermally. Single-crystal X-ray diffraction was used to determine their crystal structures. Both compounds crystallize in non-centrosymmetric space groups. The compound KSc(IO) crystallizes in the orthorhombic space group 2. The crystal structure is made up of [ScO] octahedra, [IO] trigonal pyramids, and [KO] distorted cubes. The compound KSc(IO)Cl crystallizes in the trigonal space group 3. The building blocks are [ScO] octahedra, [KO] polyhedra, and [IO] trigonal pyramids. The Cl ions act as counter ions and reside in tunnels in the crystal structure. The second harmonic generation (SHG) measurements at room temperature, using 1064 nm radiation, on polycrystalline samples show that the SHG intensities of KSc(IO) and KSc(IO)Cl are around 2.8 and 2.5 times that of KHPO (KDP), respectively. In addition, KSc(IO) and KSc(IO)Cl are phase-matchable at the fundamental wavelength of 1064 nm. The large anharmonicity in the optical response of both compounds is further supported by an anomalous temperature dependence of optical phonon frequencies as well as their enlarged intensities in Raman scattering. The latter corresponds to a very large electronic polarizability.