The bead-like LiV(PO)/NC nanofibers based on the nanocellulose from waste reed for long-life Li-ion batteries.

In this work, we firstly synthesized the high-quality nanocellulose from the waste reed, a low-cost biomass, and designed the nanostructure for energy applications. We successfully constructed the bead-like Lithium vanadium phosphate/nanofiber carbon (LVP/NC) multi-structure by self-assembly based on the nanocellulose framework. During the carbonization process, the nanocellulose turn into porous carbon nanofiber into which LVP nanoparticles can be embedded to form a bead-like structure. The unique structure can endow the effective electron contacts and ions transportation. As cathode for Li ion batteries, the composite exhibits the discharge specific capacity of 131.6 mA h/g, which is close to the theoretical specific capacity. Moreover, the composites reveal an excellent long-cycle performance. At 10 C, the capacity retention is near 90 % after 1000 cycles. With the excellent performance, this bead-like composite shows great application value and the facile synthesis strategy can be used for preparing other cathode with high performance.