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基于2,5-二氨基苯磺酸钠盐的聚酰亚胺悬浮液的电流变行为

Electrorheological Behavior of Suspensions of Polyimide-Based on the Sodium Salt of 2,5-Diaminobenzenesulfonic Acid.

作者信息

Semenov Nikolay, Danilin Alexander, Karnet Yulia, Kelbysheva Elena

机构信息

Institute of Applied Mechanics of Russian Academy of Science, Moscow 125040, Russia.

出版信息

Polymers (Basel). 2020 Apr 29;12(5):1015. doi: 10.3390/polym12051015.

Abstract

Electrorheological suspensions (ERS) of polyimide particles with organoelement fragments from the sodium salt of 2,5-diaminobenzene sulfonic acid were obtained for the first time. Their rheological and electrorheological characteristics, their dependence on the parameters of deformation, and the intensity of the external electric field were studied. It was found that the ERS of polyimide particles have a significant electrorheological response. Solid-polyimide materials were previously studied using a scanning electron microscope. The effect of the polyimide concentration on the properties of the solution was studied by spectrophotometry. It was shown that polyimide suspension is a result of increasing intensity as the electric field changes the flow type from Newtonian to pseudoplastic due to polarization of the particles and formation of the chain structures along the power lines of the electric field. The influence of temperature on the change of rheological and electrorheological properties of a polyimide ERS in constant electric fields was investigated.

摘要

首次获得了含有2,5-二氨基苯磺酸钠有机元素片段的聚酰亚胺颗粒的电流变悬浮液(ERS)。研究了它们的流变学和电流变特性、它们对变形参数的依赖性以及外部电场的强度。发现聚酰亚胺颗粒的ERS具有显著的电流变响应。先前使用扫描电子显微镜对固体聚酰亚胺材料进行了研究。通过分光光度法研究了聚酰亚胺浓度对溶液性质的影响。结果表明,聚酰亚胺悬浮液是由于电场使颗粒极化并沿电场电力线形成链状结构,从而使流动类型从牛顿流体变为假塑性流体,强度增加的结果。研究了温度对恒定电场中聚酰亚胺ERS流变学和电流变性质变化的影响。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/31a3/7284558/e02da8a27d4c/polymers-12-01015-sch001.jpg

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