Hu Xin, Wong Kin Ping, Zeng Longhui, Guo Xuyun, Liu Tong, Zhang Lei, Chen Qin, Zhang Xuefeng, Zhu Ye, Fung Kin Hung, Lau Shu Ping
Institute of Advanced Magnetic Materials, Hangzhou Dianzi University, Hangzhou 310012, China.
Department of Computing, The Hong Kong Polytechnic University, Hong Kong S.A.R., China.
ACS Nano. 2020 May 26;14(5):6276-6284. doi: 10.1021/acsnano.0c02466. Epub 2020 May 8.
Topological Dirac semimetals made of two-dimensional transition-metal dichalcogenides (TMDCs) have attracted enormous interest for use in electronic and optoelectronic devices because of their electron transport properties. As van der Waals materials with a strong interlayer interaction, these semimetals are expected to support layer-dependent plasmonic polaritons yet to be revealed experimentally. Here, we demonstrate the apparent retardation and attenuation of mid-infrared (MIR) plasmonic waves in type-II Dirac semimetal platinum tellurium (PtTe) nanoribbons and nanoflakes by near-field nanoimaging. The attenuated dispersion relations for the plasmonic modes in the PtTe nanoribbons (15-25 nm thick) extracted from the near-field standing-wave patterns are applied for the fitting of PtTe permittivity in the MIR regime, indicating that both free carriers and Dirac fermions are involved in MIR light-matter interaction in PtTe. The annihilation of plasmonic modes in the ultrathin (<10 nm) PtTe is observed and analyzed, which manifests no near-field resonant pattern due to the intrinsic layer-dependent optoelectronic properties of PtTe. These results could pave a potential wave for MIR photodetection and modulation with TMDC semimetals.
由二维过渡金属二硫属化物(TMDC)制成的拓扑狄拉克半金属因其电子输运特性而在电子和光电器件中的应用引起了极大关注。作为具有强层间相互作用的范德华材料,这些半金属有望支持尚未通过实验揭示的层依赖型等离子体极化激元。在此,我们通过近场纳米成像展示了II型狄拉克半金属铂碲(PtTe)纳米带和纳米片中红外(MIR)等离子体波的明显延迟和衰减。从近场驻波图案中提取的PtTe纳米带(15 - 25纳米厚)中等离子体模式的衰减色散关系用于拟合MIR波段的PtTe介电常数,表明自由载流子和狄拉克费米子都参与了PtTe中的MIR光与物质相互作用。观察并分析了超薄(<10纳米)PtTe中等离子体模式的湮灭,这由于PtTe固有的层依赖型光电特性而未表现出近场共振图案。这些结果可能为利用TMDC半金属进行MIR光探测和调制铺平一条潜在道路。