Ghosh Anirban, Chakraborty Dipanjan
Indian Institute of Science Education and Research Mohali, Sec. 81, S.A.S. Nagar, Knowledge City, Manauli, Punjab 140306, India.
J Chem Phys. 2020 May 7;152(17):174901. doi: 10.1063/5.0004134.
We investigate the persistence probability p(t) of the position of a Brownian particle with shape asymmetry in two dimensions. The persistence probability is defined as the probability that a stochastic variable has not changed its sign in the given time interval. We explicitly consider two cases-diffusion of a free particle and that of a harmonically trapped particle. The latter is particularly relevant in experiments that use trapping and tracking techniques to measure the displacements. We provide analytical expressions of p(t) for both the scenarios and show that in the absence of the shape asymmetry, the results reduce to the case of an isotropic particle. The analytical expressions of p(t) are further validated against numerical simulation of the underlying overdamped dynamics. We also illustrate that p(t) can be a measure to determine the shape asymmetry of a colloid and the translational and rotational diffusivities can be estimated from the measured persistence probability. The advantage of this method is that it does not require the tracking of the orientation of the particle.
我们研究了二维空间中具有形状不对称性的布朗粒子位置的持续概率(p(t))。持续概率被定义为一个随机变量在给定时间间隔内未改变其符号的概率。我们明确考虑了两种情况——自由粒子的扩散和简谐捕获粒子的扩散。后者在使用捕获和跟踪技术测量位移的实验中尤为重要。我们给出了两种情况下(p(t))的解析表达式,并表明在没有形状不对称性的情况下,结果简化为各向同性粒子的情况。(p(t))的解析表达式通过对基础过阻尼动力学的数值模拟进一步验证。我们还说明了(p(t))可以作为确定胶体形状不对称性的一种度量,并且可以从测量的持续概率估计平动和转动扩散系数。这种方法的优点是它不需要跟踪粒子的方向。