Huang Ping, Schönenberger Thomas, Cantoni Marco, Heinen Lukas, Magrez Arnaud, Rosch Achim, Carbone Fabrizio, Rønnow Henrik M
State Key Laboratory for Mechanical Behavior of Materials, Xi'an Jiaotong University, Xi'an, China.
Laboratory for Quantum Magnetism (LQM), Institute of Physics, École Polytechnique Fédérale de Lausanne (EPFL), Lausanne, Switzerland.
Nat Nanotechnol. 2020 Sep;15(9):761-767. doi: 10.1038/s41565-020-0716-3. Epub 2020 Jun 15.
The phase transition most commonly observed is probably melting, a transition from ordered crystalline solids to disordered isotropic liquids. In three dimensions, melting is a single, first-order phase transition. In two-dimensional systems, however, theory predicts a general scenario of two continuous phase transitions separated by an intermediate, oriented liquid state, the so-called hexatic phase with short-range translational and quasi-long-range orientational orders. Such hexatic phases occur in colloidal systems, Wigner solids and liquid crystals, all composed of real-matter particles. In contrast, skyrmions are countable soliton configurations with non-trivial topology and these quasi-particles can form two-dimensional lattices. Here we show, by direct imaging with cryo-Lorentz transmission electron microscopy, that magnetic field variations can tune the phase of the skyrmion ensembles in CuOSeO from a two-dimensional solid through the long-speculated skyrmion hexatic phase to a liquid. The local spin order persists throughout the process. Remarkably, our quantitative analysis demonstrates that the aforementioned topological-defect-induced crystal melting scenario well describes the observed phase transitions.
最常观察到的相变可能是熔化,即从有序的晶体固体到无序的各向同性液体的转变。在三维空间中,熔化是单一的一级相变。然而,在二维系统中,理论预测会出现一种普遍情况,即两个连续的相变被一个中间的、取向液体状态隔开,即所谓的具有短程平移和准长程取向有序的六重相。这种六重相出现在胶体系统、维格纳固体和液晶中,它们均由实物粒子组成。相比之下,斯格明子是具有非平凡拓扑结构的可数孤子构型,这些准粒子可以形成二维晶格。在这里,我们通过低温洛伦兹透射电子显微镜直接成像表明,磁场变化可以将CuOSeO中斯格明子集合体的相从二维固体通过长期推测的斯格明子六重相调谐到液体。局部自旋序在整个过程中持续存在。值得注意的是,我们的定量分析表明,上述由拓扑缺陷引起的晶体熔化情况很好地描述了观察到的相变。