Hou Yi, Yang Yong, Deng Chaoran, Li Chaojiang, Wang Chao-Fu
Temasek Laboratories, National University of Singapore, 5A Engineering Drive 1, 117411 Singapore.
ACS Appl Mater Interfaces. 2020 Jul 15;12(28):31823-31829. doi: 10.1021/acsami.0c07979. Epub 2020 Jul 1.
Understanding the physical requirements for a broad bandwidth is vital for the design of high-efficiency microwave absorber. Our recent works on silicon carbide (SiC) fiber mats-based absorbers imply that metal modification (e.g., Fe or Hf) could benefit their bandwidth effectively. For verification, we fabricated a Co/SiC fiber mat via a similar electrospinning process and subsequent pyrolysis at 1400 °C in Ar atmosphere. The results indicate that after Co modification, the SiC fiber mats show elevated permittivity and tangent loss. With a proper amount of Co adding, the mats could exhibit a wide bandwidth of around 8 GHz (ranging from 10 to 18 GHz) for effective absorption (reflection loss (RL) less than -10 dB) at 2.8 mm thickness. This is similar to our previous findings, confirming that metal modification could be an effective approach to extend the bandwidth of SiC mat absorbers. Explanations can be found through theoretical analysis with the quarter wavelength (λ/4) cancellation theory. It suggests that the declining permittivity (with the increase of frequency) is the key to keep the wavelength in material (λ) nearly unchanged within a frequency range. As a result, in this range, λ/4 cancellation could still be satisfied without changing thickness, which could explain the reasons for the broad bandwidth of metal-modified SiC fiber mats. With this model, it is further predicted that the effective absorption bandwidth could be even extended to be around 12 GHz with appropriate tangent loss. It should be emphasized that the implications obtained in this study could also be applicable to other dielectric absorbers. The requirement of permittivity and the proposed approach could serve as guidelines to achieve a wide bandwidth on a dielectric absorber relying on the λ/4 cancellation principle.
了解宽带宽的物理要求对于高效微波吸收体的设计至关重要。我们最近关于碳化硅(SiC)纤维毡基吸收体的研究表明,金属改性(如Fe或Hf)可以有效地拓宽其带宽。为了进行验证,我们通过类似的静电纺丝工艺并随后在氩气气氛中于1400℃热解制备了Co/SiC纤维毡。结果表明,经过Co改性后,SiC纤维毡的介电常数和损耗角正切有所提高。添加适量的Co后,该纤维毡在2.8mm厚度时可表现出约8GHz的宽带宽(范围为10至18GHz)以实现有效吸收(反射损耗(RL)小于-10dB)。这与我们之前的研究结果相似,证实了金属改性可能是拓宽SiC毡吸收体带宽的有效方法。可以通过基于四分之一波长(λ/4)抵消理论的理论分析找到解释。这表明介电常数的下降(随着频率的增加)是在一个频率范围内使材料中的波长(λ)几乎保持不变的关键。因此,在这个范围内,无需改变厚度仍可满足λ/4抵消,这可以解释金属改性SiC纤维毡宽带宽的原因。利用该模型进一步预测,在适当的损耗角正切情况下,有效吸收带宽甚至可以扩展到约12GHz。应该强调的是,本研究中获得的结论也可能适用于其他介电吸收体。介电常数的要求和所提出的方法可以作为依靠λ/4抵消原理在介电吸收体上实现宽带宽的指导原则。