Wu Xinfeng, Gao Yuan, Wang Ying, Jiang Tao, Yu Jinhong, Yang Ke, Zhao Yuantao, Li Wenge
College of Ocean Science and Engineering, Shanghai Maritime University, Shanghai 201306, China.
Merchant Marine College, Shanghai Maritime University, Shanghai 201306, China.
ACS Omega. 2020 Jun 1;5(23):14133-14146. doi: 10.1021/acsomega.0c01744. eCollection 2020 Jun 16.
Short carbon fiber (CF), epoxy-hardener (EP-hardener), and expanded polystyrene (EPS) beads were used to prepare CF-reinforced hollow epoxy macrospheres (CFR-HEMS) by the "rolling ball method". The multiphase epoxy syntactic foam (ESF) was prepared with CFR-HEMS, the EP-hardener system, and hollow glass microspheres (HGMS) by the "compression modeling method". In this experiment, the influences of the stacking volume fraction, wall thickness, and inner diameter of the CFR-HEMS and HGMS types and contents in the EP-hardener system on the properties of the ESF were studied. In addition, CFs with different meshes were used to reinforce hollow epoxy macrospheres (HEMS) to study the effect of different kinds of CFs on the compressive strength of the ESF. During the mixing of the EP-hardener and HGMS (EP-hardener-HGMS), 300 AW CFs with different contents were added to the system to enhance the compressive strength of the ESF. The CFR-HEMS spherical wall was combined tightly with the EP-hardener-HGMS system by a scanning electron microscope (SEM). The ESF, which has better properties relatively in the experiment, can be used in 2673 m deep water and provide 490 kg/m buoyancy, which can be of help in the preparation of buoyancy materials in detection systems and oil extraction systems in the deep sea.
采用“滚球法”,使用短碳纤维(CF)、环氧固化剂(EP-固化剂)和发泡聚苯乙烯(EPS)珠体制备了CF增强空心环氧微球(CFR-HEMS)。采用“压缩成型法”,用CFR-HEMS、EP-固化剂体系和空心玻璃微球(HGMS)制备了多相环氧复合泡沫材料(ESF)。本实验研究了CFR-HEMS和HGMS的堆积体积分数、壁厚、内径以及EP-固化剂体系中其类型和含量对ESF性能的影响。此外,使用不同目数的CF增强空心环氧微球(HEMS),以研究不同种类CF对ESF抗压强度的影响。在EP-固化剂与HGMS(EP-固化剂-HGMS)混合过程中,向体系中添加不同含量的300目CF以提高ESF的抗压强度。通过扫描电子显微镜(SEM)观察到CFR-HEMS球壁与EP-固化剂-HGMS体系紧密结合。实验中性能相对较好的ESF可用于2673米深的水中,提供490千克/立方米的浮力,有助于深海探测系统和采油系统中浮力材料的制备。