平面还是四面体？具有平面五配位碳的三元17电子CBeH簇合物。
Planar or tetrahedral? A ternary 17-electron CBeH cluster with planar pentacoordinate carbon.
作者信息
Guo Jin-Chang, Feng Lin-Yan, Barroso Jorge, Merino Gabriel, Zhai Hua-Jin
机构信息
Nanocluster Laboratory, Institute of Molecular Science, Shanxi University, Taiyuan 030006, China.
出版信息
Chem Commun (Camb). 2020 Jul 28;56(59):8305-8308. doi: 10.1039/d0cc02973d. Epub 2020 Jun 23.
PMID:32573598
Abstract
A 17-electron CBeH cluster features planar pentacoordinate carbon, owing to the 2π/6σ double aromaticity. The neutral CBeH cluster has a tetrahedral configuration despite its 18-electron counting. The latter species is governed by σ conjugation.
摘要
一个17电子的CBeH簇由于具有2π/6σ双芳香性而具有平面五配位碳。尽管中性CBeH簇的电子计数为18，但它具有四面体构型。后一种物种受σ共轭支配。
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