Hydride-encapsulated bimetallic clusters supported by 1,1-dithiolates.
作者信息
Zhong Yu-Jie, Liao Jian-Hong, Chiu Tzu-Hao, Wu Ying-Yann, Kahlal Samia, Saillard Jean-Yves, Liu C W
机构信息
Department of Chemistry, National Dong Hwa University, Hualien 974301, Taiwan, Republic of China.
出版信息
Chem Commun (Camb). 2020 Aug 21;56(65):9300-9303. doi: 10.1039/d0cc03848b. Epub 2020 Jul 15.
PMID:32666980
Abstract
Two mixed-metal hydride clusters, corresponding to x = 3 and 4, were structurally characterized from a set of atomically precise heptanuclear clusters, CuAg(H){SP(OPr)} (x = 1-6). An interstitial hydride lying at the center of a tricapped tetrahedral cage was located and refined anisotropically by using X-ray data, and its presence acertained by multinuclear NMR spectroscopy and DFT calculations.
摘要
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