六核锌（II）在具有持久室温磷光的金属有机框架中诱导密集π堆积。
Hexanuclear Zn(II)-Induced Dense π-Stacking in a Metal-Organic Framework Featuring Long-Lasting Room Temperature Phosphorescence.
作者信息
Yang Xiao-Gang, Zhai Zhi-Min, Lu Xiao-Min, Qin Jian-Hua, Li Fei-Fei, Ma Lu-Fang
机构信息
Henan Key Laboratory of Function-Oriented Porous Materials, College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471934, P. R. China.
College of Chemistry, Zhengzhou University, Zhengzhou 450001, P. R. China.
出版信息
Inorg Chem. 2020 Aug 3;59(15):10395-10399. doi: 10.1021/acs.inorgchem.0c01415. Epub 2020 Jul 23.
A new strategy to enhance the room temperature phosphorescence performance has been developed through hexanuclear Zn(II)-cluster-induced dense π-stacking in a metal-organic framework matrix. The synergistic effect of metal clusters and large overlap of π-conjugated dimers facilitate the phosphorescence emission, migration, and separation of charge carriers for excellent photocatalytic activity.
通过六核锌（II）簇诱导金属有机框架基质中的密集π-堆积，开发了一种提高室温磷光性能的新策略。金属簇的协同效应和π共轭二聚体的大重叠促进了磷光发射、电荷载流子的迁移和分离，从而具有优异的光催化活性。
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