Jiao Wan, Hagler Gayle, Williams Ronald, Sharpe Robert, Brown Ryan, Garver Daniel, Judge Robert, Caudill Motria, Rickard Joshua, Davis Michael, Weinstock Lewis, Zimmer-Dauphinee Susan, Buckley Ken
US Environmental Protection Agency (EPA), Office of Research and Development, Research Triangle Park, NC 27711, USA.
ARCADIS US, Inc., Durham, NC 27713, USA.
Atmos Meas Tech. 2016 Nov 1;9(11):5281-5292. doi: 10.5194/amt-9-5281-2016.
Advances in air pollution sensor technology have enabled the development of small and low-cost systems to measure outdoor air pollution. The deployment of a large number of sensors across a small geographic area would have potential benefits to supplement traditional monitoring networks with additional geographic and temporal measurement resolution, if the data quality were sufficient. To understand the capability of emerging air sensor technology, the Community Air Sensor Network (CAIRSENSE) project deployed low-cost, continuous, and commercially available air pollution sensors at a regulatory air monitoring site and as a local sensor network over a surrounding ∼ 2 km area in the southeastern United States. Collocation of sensors measuring oxides of nitrogen, ozone, carbon monoxide, sulfur dioxide, and particles revealed highly variable performance, both in terms of comparison to a reference monitor as well as the degree to which multiple identical sensors produced the same signal. Multiple ozone, nitrogen dioxide, and carbon monoxide sensors revealed low to very high correlation with a reference monitor, with Pearson sample correlation coefficient () ranging from 0.39 to 0.97, 0.25 to 0.76, and 0.40 to 0.82, respectively. The only sulfur dioxide sensor tested revealed no correlation ( < 0.5) with a reference monitor and erroneously high concentration values. A wide variety of particulate matter (PM) sensors were tested with variable results - some sensors had very high agreement (e.g., = 0.99) between identical sensors but moderate agreement with a reference PM monitor (e.g., = 0.65). For select sensors that had moderate to strong correlation with reference monitors ( > 0.5), step-wise multiple linear regression was performed to determine if ambient temperature, relative humidity (RH), or age of the sensor in number of sampling days could be used in a correction algorithm to improve the agreement. Maximum improvement in agreement with a reference, incorporating all factors, was observed for an NO sensor (multiple correlation coefficient R = 0.57, R = 0.81); however, other sensors showed no apparent improvement in agreement. A four-node sensor network was successfully able to capture ozone (two nodes) and PM (four nodes) data for an 8-month period of time and show expected diurnal concentration patterns, as well as potential ozone titration due to nearby traffic emissions. Overall, this study demonstrates the performance of emerging air quality sensor technologies in a real-world setting; the variable agreement between sensors and reference monitors indicates that in situ testing of sensors against benchmark monitors should be a critical aspect of all field studies.
空气污染传感器技术的进步推动了小型低成本室外空气污染测量系统的发展。如果数据质量足够,在小地理区域内大量部署传感器可能有助于用额外的地理和时间测量分辨率补充传统监测网络。为了解新兴空气传感器技术的能力,社区空气传感器网络(CAIRSENSE)项目在美国东南部的一个监管空气监测站点以及周围约2公里区域内作为本地传感器网络部署了低成本、连续且商用的空气污染传感器。对测量氮氧化物、臭氧、一氧化碳、二氧化硫和颗粒物的传感器进行并置,结果显示无论是与参考监测仪相比,还是多个相同传感器产生相同信号的程度,其性能都存在很大差异。多个臭氧、二氧化氮和一氧化碳传感器与参考监测仪的相关性显示为低到非常高,皮尔逊样本相关系数()分别为0.39至0.97、0.25至0.76和0.40至0.82。测试的唯一二氧化硫传感器与参考监测仪无相关性(<0.5),且浓度值错误地偏高。对多种颗粒物(PM)传感器进行了测试,结果各不相同——一些传感器在相同传感器之间具有非常高的一致性(例如,=0.99),但与参考PM监测仪的一致性一般(例如,=0.65)。对于与参考监测仪具有中度至强相关性(>0.5)的选定传感器,进行逐步多元线性回归以确定环境温度、相对湿度(RH)或传感器按采样天数计算的使用时长是否可用于校正算法以提高一致性。对于一个NO传感器,纳入所有因素后与参考的一致性得到最大改善(多元相关系数R=0.57,R=0.81);然而,其他传感器的一致性没有明显改善。一个四节点传感器网络成功地在8个月的时间内捕获了臭氧(两个节点)和PM(四个节点)数据,并显示出预期的日浓度模式,以及由于附近交通排放导致的潜在臭氧滴定。总体而言,本研究展示了新兴空气质量传感器技术在实际环境中的性能;传感器与参考监测仪之间的不一致表明,针对基准监测仪对传感器进行现场测试应是所有实地研究的关键环节。