Ksiazek Marzanna, Boron Lukasz, Tchorz Adam
Department of Non-Ferrous Metals, AGH University of Science and Technology, 30 Mickiewicza Ave., 30-059 Cracow, Poland.
Łukasiewicz Research Network-Cracow Technology Institute, 73 Zakopianska St., 30-418 Cracow, Poland.
Materials (Basel). 2020 Sep 16;13(18):4122. doi: 10.3390/ma13184122.
Alumina oxide coatings are widely used in many industrial applications to improve corrosion protection, wear and erosion resistances, and thermal insulation of metallic surfaces. The paper presents study of the microstructure, mechanical, and wear properties of HVOF (high velocity oxy-fuel process) sprayed of AlO-15 wt.% TiO coating with the NiAl interlayer on the surface of Al-Si alloy castings. The microstructure of AlO-15 wt.% TiO/NiAl coating was characterized by light microscopy, X-ray diffraction (XRD), scanning electron microscope (SEM), and energy dispersive X-ray spectroscopy (EDS). The analysis of the microstructure showed the formation of coating with low porosity, compact structure, good adhesion to the substrate with typical lamellar structure composed of a solid phase consisting of compounds included in the coating material and their phase variations. For analysis of the adhesion of coatings to the substrate, the scratch test was applied. An assessment of the erosive wear resistance of coatings was also carried out, confirming the significant impact of the interlayer as well as the microstructure and phase composition of the oxide coating on the wear resistance of the tested coating system. Moreover, the results were discussed in relation to the bending strength test, including cracks and delamination in the system of the AlO-15 wt.% TiO/NiAl/Al-Si alloy as microhardness and erosion resistance of the coating. It was found that the introduction of the NiAl metallic interlayer significantly increased resistance to cracking and wear behavior in the studied system.
氧化铝涂层广泛应用于许多工业领域,以提高金属表面的耐腐蚀性能、耐磨和抗侵蚀性能以及隔热性能。本文研究了在Al-Si合金铸件表面采用高速氧燃料喷涂工艺(HVOF)制备的含15 wt.% TiO的AlO涂层与NiAl中间层的微观结构、力学性能和耐磨性能。通过光学显微镜、X射线衍射(XRD)、扫描电子显微镜(SEM)和能量色散X射线光谱仪(EDS)对含15 wt.% TiO的AlO/NiAl涂层的微观结构进行了表征。微观结构分析表明,涂层形成了低孔隙率、致密的结构,与具有典型层状结构的基体具有良好的附着力,该层状结构由涂层材料中所含化合物及其相变体组成的固相构成。为了分析涂层与基体的附着力,进行了划痕试验。还对涂层的抗冲蚀磨损性能进行了评估,证实了中间层以及氧化物涂层的微观结构和相组成对测试涂层系统耐磨性的显著影响。此外,还结合弯曲强度试验对结果进行了讨论,包括AlO-15 wt.% TiO/NiAl/Al-Si合金系统中的裂纹和分层,以及涂层的显微硬度和耐蚀性。研究发现,引入NiAl金属中间层显著提高了所研究系统的抗开裂性能和耐磨性能。