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金属卤化物钙钛矿纳米棒:形状至关重要。

Metal Halide Perovskite Nanorods: Shape Matters.

作者信息

Zhang Chengxi, Chen Jiayi, Wang Sheng, Kong Lingmei, Lewis Simon W, Yang Xuyong, Rogach Andrey L, Jia Guohua

机构信息

Key Laboratory of Advanced Display and System Applications of Ministry of Education, Shanghai University, 149 Yanchang Road, Shanghai, 200072, P. R. China.

Curtin Institute of Functional Molecules and Interfaces, School of Molecular and Life Sciences, Curtin University, GPO Box U1987, Perth, WA, 6845, Australia.

出版信息

Adv Mater. 2020 Nov;32(46):e2002736. doi: 10.1002/adma.202002736. Epub 2020 Sep 28.

Abstract

Quasi-1D metal halide perovskite nanorods (NRs) are emerging as a type of materials with remarkable optical and electronic properties. Research into this field is rapidly expanding and growing in the past several years, with significant advances in both mechanistic studies of their growth and widespread possible applications. Here, the recent advances in 1D metal halide perovskite nanocrystals (NCs) are reviewed, with a particular emphasis on NRs. At first, the crystal structures of perovskites are elaborated, which is followed by a review of the major synthetic approaches toward perovskite NRs, such as wet-chemical synthesis, substrate-assisted growth, and anion exchange reactions, and discussion of the growth mechanisms associated with each synthetic method. Then, thermal and aqueous stability and the linear polarized luminescence of perovskite NRs are considered, followed by highlighting their applications in solar cells, light-emitting diodes, photodetectors/phototransistors, and lasers. Finally, challenges and future opportunities in this rapidly developing research area are summarized.

摘要

准一维金属卤化物钙钛矿纳米棒(NRs)正作为一种具有卓越光学和电子特性的材料崭露头角。在过去几年中,该领域的研究迅速扩展并不断发展,在其生长机理研究和广泛的潜在应用方面都取得了重大进展。在此,对一维金属卤化物钙钛矿纳米晶体(NCs)的最新进展进行综述,尤其着重于纳米棒。首先阐述钙钛矿的晶体结构,随后综述制备钙钛矿纳米棒的主要合成方法,如湿化学合成、衬底辅助生长和阴离子交换反应,并讨论与每种合成方法相关的生长机制。接着考虑钙钛矿纳米棒的热稳定性和水稳定性以及线性偏振发光,随后重点介绍它们在太阳能电池、发光二极管、光电探测器/光电晶体管和激光器中的应用。最后总结了这个快速发展的研究领域中的挑战和未来机遇。

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