Zhu Yong-Hui, Wang Qian, Huang Ling, Yin Si-Jia, Li Li, Wang Yang-Jun
Institute of Environmental Pollution and Health, School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, China.
Huan Jing Ke Xue. 2020 Aug 8;41(8):3511-3517. doi: 10.13227/j.hjkx.202001006.
Intermediate volatility organic compounds (IVOCs) are important precursors of secondary organic aerosols (SOA) but are currently not included in the conventional emissions inventories. Biomass burning represents an important source of IVOCs that could contribute to SOA formation. This study estimated the IVOC emissions from biomass burning in the Yangtze River Delta (YRD) region from 2010 to 2018 based on the fire inventory from NCAR (FINN) and the IVOCs/primary organic aerosol (POA) ratio reported in literature. During this period, the total number of fire events over the YRD region presented a declining trend, with an average of 10 fire events detected per year. During 2016-2018, the average number of fire events was approximately 6000 per year, which was 60% less than that prior to 2016. In terms of the monthly variation, the period from May to August was the period with the most fires observed, which was followed by a small peak in October. The results calculated based on the IVOCs/POA ratio method showed that the IVOC emissions from biomass burning exhibited large differences with different combinations of POA/OC and IVOCs/POA ratios, ranging from a maximum of 305.7×10 t to as small as 10.5×10 t. Monte Carlo simulation revealed that the uncertainties associated with the IVOCs/POA ratio method range from -99% to 68%.
中等挥发性有机化合物(IVOCs)是二次有机气溶胶(SOA)的重要前体物,但目前未纳入传统排放清单。生物质燃烧是可能促成SOA形成的IVOCs的一个重要来源。本研究基于美国国家大气研究中心(NCAR)的火灾清单(FINN)以及文献报道的IVOCs/一次有机气溶胶(POA)比率,估算了2010年至2018年长江三角洲(YRD)地区生物质燃烧产生的IVOCs排放量。在此期间,YRD地区的火灾事件总数呈下降趋势,平均每年检测到10起火灾事件。在2016 - 2018年期间,火灾事件的平均数量约为每年6000起,比2016年之前减少了60%。就月度变化而言,5月至8月是观测到火灾最多的时期,其次是10月出现一个小高峰。基于IVOCs/POA比率方法计算的结果表明,生物质燃烧产生的IVOCs排放量在POA/OC和IVOCs/POA比率的不同组合下存在很大差异,范围从最大的305.7×10吨到小至10.5×10吨。蒙特卡罗模拟表明,与IVOCs/POA比率方法相关的不确定性范围为 - 99%至68%。