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含铬皮革边角料的增值利用:胶原水解物插层电纺纳米纤维的可持续吸音材料。

Chromium containing leather trimmings valorization: Sustainable sound absorber from collagen hydrolysate intercalated electrospun nanofibers.

机构信息

Inorganic and Physical Chemistry Laboratory, CSIR-Central Leather Research Institute, Adyar, Chennai 600020, India.

Inorganic and Physical Chemistry Laboratory, CSIR-Central Leather Research Institute, Adyar, Chennai 600020, India.

出版信息

J Hazard Mater. 2021 Mar 5;405:124231. doi: 10.1016/j.jhazmat.2020.124231. Epub 2020 Oct 15.

Abstract

Developing value-added material from industrial waste is one of the sustainable ways of recycling solid waste produced from the leather industry. Noise which makes a considerable negative impact in the day to day life of people needs immediate attention where the sound absorbers play a vital role. Nanofibers can be used as sound absorbers due to their properties like porosity and high surface area. In this study, collagen hydrolysate extracted from waste leather trimmings was utilized to produce multilayer hybrid sound-absorbing material. Collagen hydrolysate was electrospun along with polyvinyl alcohol (PVA) and the layer was sandwiched between polyacrylonitrile (PAN) nanofibrous layers. The hierarchical structure of the composite is more porous on outer layers than medium porous inner collagen hydrolysate- PVA layer. The hybrid material was characterized using various experimental techniques and the sound absorption was measured using two-microphone impedance tube method. From acoustic measurements, it was revealed that the composite showed improved sound absorption in the frequency range of 800-2500 Hz due to its varying pore size. Hence, the leather trimmings as a component of sound-absorbing material creates an innovative solution for discarded leather waste and they can be used in practical applications like room acoustics.

摘要

从工业废料中开发增值材料是回收皮革工业产生的固体废物的可持续方法之一。噪声在人们的日常生活中产生了相当大的负面影响,需要立即引起关注,而吸声材料则起着至关重要的作用。纳米纤维由于其多孔性和高比表面积等特性,可以用作吸声材料。在这项研究中,从废皮革修剪物中提取的胶原水解物被用于生产多层混合吸声材料。胶原水解物与聚乙烯醇(PVA)一起进行静电纺丝,然后将其夹在聚丙烯腈(PAN)纳米纤维层之间。该复合材料的分层结构在外层比中层多孔的胶原水解物-PVA 层更具多孔性。通过各种实验技术对复合材料进行了表征,并使用双传声器阻抗管法测量了吸声性能。通过声学测量,由于其不同的孔径,该复合材料在 800-2500 Hz 的频率范围内显示出了更好的吸声性能。因此,皮革修剪物作为吸声材料的一部分,为废弃皮革废物创造了一个创新的解决方案,它们可以在房间声学等实际应用中使用。

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