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未增容的聚己二酸/对苯二甲酸丁二醇酯/聚乳酸共混物:可制造性、相容性及性能

Uncompatibilized PBAT/PLA Blends: Manufacturability, Miscibility and Properties.

作者信息

Su Shen, Duhme Mona, Kopitzky Rodion

机构信息

Department of Circular and Bio-based Plastics, Fraunhofer UMSICHT, Institute for Environment, Safety and Energy Technology, Osterfelder Str. 3, 46047 Oberhausen, Germany.

Department of Mechanical Engineering, Ruhr-University Bochum, Universitaetsstr. 150, 44780 Bochum, Germany.

出版信息

Materials (Basel). 2020 Oct 31;13(21):4897. doi: 10.3390/ma13214897.

Abstract

Polymer blends of poly(butylene adipate-co-terephthalate) (PBAT) and polylactide (PLA) have been drawn attention due to the application potential as packaging or agricultural films. This study aims to determine the manufacturability, miscibility and mechanical properties of uncompatibilized PBAT/PLA blends prepared using different techniques. First, PBAT and PLA are melt-blended in a wide range of ratios from 90/10 to 10/90. The compounds are then processed into pressed panels, flat films and blown films. Finally, the thermal, morphological, rheological and mechanical properties of these blends are investigated. PBAT/PLA blends have a small difference of solubility parameters, predicting theoretically good miscibility. However, they show two almost unchanged glass transition temperatures in the DSC, phase separation in SEM and two relaxation mechanisms in the Cole-Cole plot. The phase morphology varies depending on both the blend ratios and the preparation techniques. Tensile tests indicate that with increasing PLA content the elongation at break decreases. A good correlation between the elongation at break and the tear propagation resistance is found. Furthermore, the trouser tear method is proven to be more applicable to differentiate highly extensible blown films compared with the Elmendorf tear method.

摘要

聚(己二酸丁二醇酯-对苯二甲酸丁二醇酯)(PBAT)和聚乳酸(PLA)的聚合物共混物因其作为包装或农用薄膜的应用潜力而受到关注。本研究旨在确定采用不同技术制备的未增容PBAT/PLA共混物的可制造性、相容性和机械性能。首先,将PBAT和PLA按90/10至10/90的广泛比例进行熔融共混。然后将这些混合物加工成压制板、平膜和吹塑薄膜。最后,对这些共混物的热性能、形态学性能、流变性能和机械性能进行研究。PBAT/PLA共混物的溶解度参数差异较小,理论上预测具有良好的相容性。然而,它们在差示扫描量热法(DSC)中显示出两个几乎不变的玻璃化转变温度,在扫描电子显微镜(SEM)中出现相分离,并且在Cole-Cole图中显示出两种松弛机制。相形态取决于共混比例和制备技术。拉伸试验表明,随着PLA含量的增加,断裂伸长率降低。发现断裂伸长率与抗撕裂传播性之间具有良好的相关性。此外,与埃尔门多夫撕裂法相比,裤形撕裂法被证明更适用于区分高拉伸吹塑薄膜。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aa6d/7662590/8c3a3c893cc8/materials-13-04897-g001.jpg

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