Deng Jinyuan, Xiao Shuning, Wang Bei, Li Qian, Li Guisheng, Zhang Dieqing, Li Hexing
Key Laboratory of Resource Chemistry of Ministry of Education, Shanghai Key Laboratory of Rare Earth Functional Materials, Shanghai Normal University, Shanghai 200234, China (PRC).
ACS Appl Mater Interfaces. 2020 Nov 18;12(46):51537-51545. doi: 10.1021/acsami.0c15694. Epub 2020 Nov 8.
Steam generation and photocatalytic degradation of organic pollutants based on solar light are regarded as two important strategies for addressing the water scarcity issues. The water evaporation efficiency was greatly inhibited by the high cost, low stability, and low efficiencies of solar light absorption and photothermal conversion of photothermal materials. Moreover, volatile organic compounds (VOCs) are easily volatilized and enriched in as-distilled water during the photothermal process. Inspired by the structure of biomass materials in nature, a bifunctional solar light-driven steam generation and VOC removal microreactor was explored by coating commercial TiO (P25) powders on a carbonized biomass waste . With the 3D aligned porous carbon architectures, this microreactor exhibited both a high water evaporation rate (37.0 kg m h) and a high energy conversion efficiency (91.2%) under simulated sunlight irradiation (light intensity = 25.5 kW m). A high VOC removal rate (80.9% in 40 min) was also achieved during the steam generation process choosing phenol as the probe pollutant molecules. The nature-inspired designing concept and bifunctional microreactor in this study may open up a new strategy for producing clean distilled water from seawater with an efficient removal of VOCs.
基于太阳光的蒸汽产生和有机污染物的光催化降解被视为解决水资源短缺问题的两种重要策略。光热材料的高成本、低稳定性以及太阳光吸收和光热转换的低效率极大地抑制了水蒸发效率。此外,在光热过程中,挥发性有机化合物(VOCs)很容易在蒸馏水中挥发和富集。受自然界生物质材料结构的启发,通过在碳化生物质废料上涂覆商用TiO(P25)粉末,探索了一种双功能太阳光驱动的蒸汽产生和VOC去除微反应器。借助三维排列的多孔碳结构,该微反应器在模拟太阳光照射(光强 = 25.5 kW m)下表现出高水蒸发速率(37.0 kg m h)和高能量转换效率(91.2%)。在蒸汽产生过程中,选择苯酚作为探针污染物分子,也实现了较高的VOC去除率(40分钟内为80.9%)。本研究中受自然启发的设计理念和双功能微反应器可能为从海水中生产清洁蒸馏水并有效去除VOCs开辟一种新策略。