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Production of Multiply Charged Argon Ions in Moderate Nanosecond Laser Fields: An Open Question or a Forgone Conclusion?

作者信息

Yao Yuzhong, Zhang Jie, Pandey Rahul, Kong Wei

机构信息

Department of Chemistry, Oregon State University, Corvallis, Oregon 97331, United States.

出版信息

J Phys Chem Lett. 2020 Nov 19;11(22):9971-9974. doi: 10.1021/acs.jpclett.0c02948.

Abstract

We reply to the Viewpoint by Vatsa and Mathur on our publication reporting the observation of multiply charged atomic ions from argon clusters doped with aromatic chromophores in a moderate nanosecond laser field. Vatsa and Mathur raised three concerns about the proposed explanation and offered additional ideas for the reported process. We agree with some of their concerns and welcome the addition of information, and we also clarify a few misunderstandings of our intention, perhaps caused by our implicit assumption of contextual relations. While the experimental results are indisputable, the interpretation is still a topic of debate, subject to further experimental investigations and theoretical modeling.

摘要

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本文引用的文献

1
Coulomb Explosion in Nanosecond Laser Fields.
J Phys Chem Lett. 2020 Feb 6;11(3):1100-1105. doi: 10.1021/acs.jpclett.0c00092. Epub 2020 Jan 27.
2
Ionization Avalanching in Clusters Ignited by Extreme-Ultraviolet Driven Seed Electrons.
Phys Rev Lett. 2016 Jan 22;116(3):033001. doi: 10.1103/PhysRevLett.116.033001. Epub 2016 Jan 19.
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Mass spectrometric and charge density studies of organometallic clusters photoionized by gigawatt laser pulses.
Mass Spectrom Rev. 2017 Mar;36(2):188-212. doi: 10.1002/mas.21469. Epub 2015 May 11.
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Multiphoton ionization and Coulomb explosion of C2H5Br clusters: a mass spectrometric and charge density study.
Rapid Commun Mass Spectrom. 2011 Apr 30;25(8):1028-36. doi: 10.1002/rcm.4951. Epub 2011 Mar 29.
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Two very efficient nonlinear laser absorption mechanisms in clusters.
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