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使用HPO活化剂由种子制备活性炭及其对亚甲基蓝和孔雀石绿的吸附

Production of activated carbon from seeds using HPO activator and methylene blue and malachite green adsorption.

作者信息

Baytar Orhan, Ceyhan A Abdullah, Şahin Ömer

机构信息

Department of Chemical Engineering, Faculty of Engineering, Siirt University, Siirt, Turkey.

Department of Chemical Engineering, Faculty of Natural and Engineering Sciences, Konya Technical University, Konya, Turkey.

出版信息

Int J Phytoremediation. 2021;23(7):693-703. doi: 10.1080/15226514.2020.1849015. Epub 2020 Nov 21.

Abstract

In this study, activated carbon was obtained from seeds and its usability in the adsorption of methylene blue (MB) and malachite green (MG) from aqueous solution was investigated. Activated carbon was synthesized by chemical activation method using HPO as an activator. In the synthesis of the activated carbon, the effects of various parameters such as the rate of impregnation, duration of activation, temperature of activation and duration of activation were investigated. The characterization of the synthesized activated carbons was carried out by FTIR, SEM and BET analyses and the surface area of the produced activated carbon was determined to be 1,194 m g. The effects of solution initial pH, solution initial concentration and amount of activated carbon on MB and MG adsorption were investigated. The adsorption capacity was found to be higher when the pH of the solution was 8 for MB and 4 for MG. The adsorption kinetics of MB and MG were found to fit the Elovich kinetic model and pseudo-first-order kinetic model, respectively. Adsorption equilibrium data were found to be compatible with Langmuir isotherm for both dyes. According to the Langmuir isotherm, adsorption capacity was found to be 72 mg/g and 115 mg/g for MB and MG, respectively. Activated carbon was obtained from seeds and its usability in the adsorption of methylene blue (MB) and malachite green (MG) from aqueous solution was investigated. A high surface area activated carbon was synthesized. The surface area of the produced activated carbon was determined to be 1,194 m g. According to the Langmuir isotherm, adsorption capacity was found to be 72 mg/g and 115 mg/g for MB and MG, respectively. It has been determined that the adsorption capacity of synthesized activated carbon is high.

摘要

在本研究中,从种子中获得了活性炭,并研究了其对水溶液中亚甲基蓝(MB)和孔雀石绿(MG)的吸附可用性。采用化学活化法,以HPO作为活化剂合成了活性炭。在活性炭的合成过程中,研究了浸渍率、活化时间、活化温度和活化时长等各种参数的影响。通过傅里叶变换红外光谱(FTIR)、扫描电子显微镜(SEM)和比表面积分析仪(BET)分析对合成的活性炭进行了表征,所制备活性炭的表面积测定为1194 m²/g。研究了溶液初始pH值、溶液初始浓度和活性炭用量对MB和MG吸附的影响。发现当溶液pH值为8时对MB的吸附容量较高,而对MG则在pH值为4时吸附容量较高。发现MB和MG的吸附动力学分别符合埃洛维奇动力学模型和准一级动力学模型。两种染料的吸附平衡数据均与朗缪尔等温线相符。根据朗缪尔等温线,MB和MG的吸附容量分别为72 mg/g和115 mg/g。从种子中获得了活性炭,并研究了其对水溶液中亚甲基蓝(MB)和孔雀石绿(MG)的吸附可用性。合成了一种高比表面积活性炭。所制备活性炭的表面积测定为1194 m²/g。根据朗缪尔等温线,MB和MG的吸附容量分别为72 mg/g和115 mg/g。已确定合成活性炭的吸附容量较高。

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