构建具有近红外发光传感性能的 18 金属钕（III）纳米环对抗生素的检测。
Construction of a 18-Metal Neodymium(III) Nanoring with NIR Luminescent Sensing to Antibiotics.
机构信息
College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035, P. R. China.
Department of Chemistry and Biochemistry, The University of Texas at Austin, 1 University Station A5300, Austin, Texas 78712, United States.
出版信息
Inorg Chem. 2020 Dec 7;59(23):17608-17613. doi: 10.1021/acs.inorgchem.0c02840. Epub 2020 Nov 23.
One 18-metal Nd(III) nanoring, [Nd(L)(HL)(OAc)(MeOH)(EtOH)(HO)]·2(MeOH)·6(HO) (), was constructed by the use of a hexadentate Schiff base ligand. For , the near-infrared (NIR) luminescence of Nd(III) was detected under the excitation of absorption band at 371 nm. The study of luminescent sensing properties exhibits that, even with the existence of other antibiotics, this Nd(III) nanoring displays high sensitivity and selectivity to nitrofuran antibiotics (NFAs). The luminescence quenching constants and limits of detection of to NFAs are found to be 1.4 × 10 to 3.5 × 10 M and 0.9-2.2 μM, respectively.
一个 18 金属钕(III)纳米环，[Nd(L)(HL)(OAc)(MeOH)(EtOH)(HO)]·2(MeOH)·6(HO) ()，是通过使用六齿席夫碱配体构建的。对于，在 371nm 吸收带的激发下检测到了 Nd(III)的近红外(NIR)发光。发光传感性能的研究表明，即使存在其他抗生素，这种 Nd(III)纳米环对硝基呋喃类抗生素(NFAs)也表现出高灵敏度和选择性。发现对 NFAs 的荧光猝灭常数和检测限分别为 1.4×10 到 3.5×10 M 和 0.9-2.2μM。
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