Lingamdinne Lakshmi Prasanna, Lee Suhyun, Choi Jong-Soo, Lebaka Veeranjaneya Reddy, Durbaka Vijaya Raghava Prasad, Koduru Janardhan Reddy
Department of Environmental Engineering, Kwangwoon University, Seoul, 01897, Republic of Korea.
Department of Microbiology, Yogi Vemana University, Kadapa, Andhra Pradesh, 516005, India.
J Hazard Mater. 2021 Jan 15;402:123882. doi: 10.1016/j.jhazmat.2020.123882. Epub 2020 Sep 6.
Potential of the magnetic hollow-sphere nanocomposite, graphene oxide-gadolinium oxide (GO-GdO) for arsenic (As) removal from real field water with developing a continuous operating system and antimicrobial activity were investigated. The characterization results suggest that the prepared GO-GdO is a hallow sphere wool-like nanocomposite having 50.91 m g surface area. The sorption studies revealed that a high adsorption capacity (216.70 mg g) can be achieved using GO-GdO (0.1 g L) at a pH of 6.0, and temperature of 293 K. The main and novel observations from the loading of GdO are that the GO adsorption efficiency, adsorbent separation rate from aqueous solutions, and the stability of the composite have been altered. Thus, the developed material can overcome the separation and stability issues associated with the bare GO, and exhibits an enhanced adsorption capacity toward arsenic was higher or comparable with existing magnetic material. In addition, the developed adsorption method was well applied for real field water samples collected from the mining area of South Korea where the GO-GdO can reduce the quantity of arsenic under the maximum accepted concentration of arsenic considered fit for drinking water stipulated by environmental protection agencies. Furthermore, the GO-GdO nanocomposite shows a high bacterial photocatalytic inactivation and was comparable with other reports.
研究了磁性空心球纳米复合材料氧化石墨烯-氧化钆(GO-GdO)在开发连续操作系统的情况下从实际现场水中去除砷(As)的潜力以及抗菌活性。表征结果表明,制备的GO-GdO是一种表面积为50.91 m²/g的空心球状羊毛状纳米复合材料。吸附研究表明,在pH为6.0、温度为293 K的条件下,使用0.1 g/L的GO-GdO可实现较高的吸附容量(216.70 mg/g)。负载GdO的主要和新颖观察结果是,GO的吸附效率、从水溶液中的吸附剂分离速率以及复合材料的稳定性都发生了变化。因此,所开发的材料可以克服与裸GO相关的分离和稳定性问题,并且对砷表现出增强的吸附容量,该容量高于或与现有磁性材料相当。此外,所开发的吸附方法很好地应用于从韩国矿区采集的实际现场水样,其中GO-GdO可以将砷的含量降低到环境保护机构规定的适合饮用水的砷最大允许浓度以下。此外,GO-GdO纳米复合材料表现出较高的细菌光催化失活率,与其他报道相当。