Park JangHyun, Park JinHo, Jung MyeongGyu
Korea Institute of Future Convergence Technology, Hankyong National University, 327 Jungang-ro, Anseong 17579, Korea.
Materials (Basel). 2020 Nov 28;13(23):5430. doi: 10.3390/ma13235430.
When an additive is used to replace a certain amount of cement, a concrete pore structure becomes dense. Thus, it results in inhibiting the penetration of chlorine ions and suppressing corrosion of reinforcing bars. However, the pH level of the concrete decreases, and it deteriorates the performance of the passive film formed on the surface of the rebars embedded in the concrete. Therefore, in this study, the service lives of reinforced concrete containing different types of concrete binders were predicted and compared. The chloride ion diffusion coefficients of concretes with various binders were measured, and the critical chloride content of the rebar was assessed by the real-time monitoring on the corrosion initiation time of the rebar embedded in concrete. Moreover, Fick's 2nd law was applied to predict when the chloride content at the 40 mm depth of cover reached the critical chloride content based on the chloride ion diffusion coefficient. It was observed that the service life of S6 (OPC 40% + GGBFS 60%) was the highest, followed by TBC (OPC 40% + GGBFS 40% + FA 20%), S3 (OPC 70% + GGBFS 30%), and OPC (OPC 100%).
当使用一种添加剂替代一定量的水泥时,混凝土的孔隙结构会变得致密。因此,这会抑制氯离子的渗透并抑制钢筋的腐蚀。然而,混凝土的pH值会降低,这会使混凝土中嵌入的钢筋表面形成的钝化膜性能变差。因此,在本研究中,对含有不同类型混凝土胶凝材料的钢筋混凝土的使用寿命进行了预测和比较。测量了含有各种胶凝材料的混凝土的氯离子扩散系数,并通过实时监测混凝土中嵌入钢筋的腐蚀起始时间来评估钢筋的临界氯离子含量。此外,基于氯离子扩散系数,应用菲克第二定律预测保护层深度40mm处的氯离子含量何时达到临界氯离子含量。结果发现,S6(40%普通硅酸盐水泥+60%粒化高炉矿渣粉)的使用寿命最高,其次是TBC(40%普通硅酸盐水泥+40%粒化高炉矿渣粉+20%粉煤灰)、S3(70%普通硅酸盐水泥+30%粒化高炉矿渣粉)和OPC(100%普通硅酸盐水泥)。