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不同来源再生混凝土集料的化学-矿物学特征及其在沥青混合料中的潜在反应

The Chemical-Mineralogical Characterization of Recycled Concrete Aggregates from Different Sources and Their Potential Reactions in Asphalt Mixtures.

作者信息

Sánchez-Cotte Edgar H, Pacheco-Bustos Carlos Albeiro, Fonseca Ana, Triana Yaneth Pineda, Mercado Ronald, Yepes-Martínez Julián, Lagares Espinoza Ricardo Gabriel

机构信息

Facultad Tecnológica, Universidad Distrital Francisco José de Caldas, Cl. 68D Bis A Sur, Bogotá 49F-70, Colombia.

División de Ingeniería, Universidad del Norte-km 5 Vía Puerto Colombia, Barranquilla, Colombia.

出版信息

Materials (Basel). 2020 Dec 8;13(24):5592. doi: 10.3390/ma13245592.

Abstract

The incorporation of a recycled concrete aggregate (RCA) as a replacement of natural aggregates (NA) in road construction has been the subject of recent research. This tendency promotes sustainability, but its use depends mainly on the final product's properties, such as chemical stability. This study evaluates the physical and chemical properties of RCAs from two different sources in comparison with the performance of NA. One RCA was obtained from the demolition of a building (recycled concrete aggregate of a building-RCAB) and another RCA from the rehabilitation of a Portland cement concrete pavement (recycled concrete aggregate from a pavement-RCAP). Characterization techniques such as X-ray fluorescence (XRF), X-ray diffraction (XRD), UV spectroscopy, and atomic absorption spectrometry were used to evaluate the RCAs' coarse fractions for chemical potential effects on asphalt mixtures. NA was replaced with RCA at 15%, 30%, and 45% for each size of the coarse fractions (retained 19.0, 12.5, 9.5, and 4.75 sieves in mm). The mineralogical characterization results indicated the presence of quartz (SiO) and calcite (CaCO) as the most significant constituents of the aggregates. XFR showed that RCAs have lower levels of CaO and AlO concerning NA. Potential reactions in asphalt mixtures by nitration, sulfonation, amination of organic compounds, and reactions by alkaline activation in the aggregates were discarded due to the minimum concentration of components such as NO, (-SOH), (-SOCl), and (Na) in the aggregates. Finally, this research concludes that studied RCAs might be used as replacements of coarse aggregate in asphalt mixtures since chemical properties do not affect the overall chemical stability of the asphalt mixture.

摘要

在道路建设中使用再生混凝土骨料(RCA)替代天然骨料(NA)已成为近期研究的主题。这种趋势促进了可持续性,但其使用主要取决于最终产品的性能,如化学稳定性。本研究评估了来自两种不同来源的RCA的物理和化学性质,并与NA的性能进行了比较。一种RCA是从建筑物拆除中获得的(建筑物再生混凝土骨料-RCAB),另一种RCA是从波特兰水泥混凝土路面修复中获得的(路面再生混凝土骨料-RCAP)。采用X射线荧光光谱法(XRF)、X射线衍射法(XRD)、紫外光谱法和原子吸收光谱法等表征技术,评估了RCA粗集料对沥青混合料的化学潜在影响。对于每种尺寸的粗集料(保留19.0、12.5、9.5和4.75毫米筛孔),用RCA分别替代NA的比例为15%、30%和45%。矿物学表征结果表明,石英(SiO)和方解石(CaCO)是骨料中最主要的成分。XFR结果表明,与NA相比,RCA中CaO和AlO的含量较低。由于骨料中NO、(-SOH)、(-SOCl)和(Na)等成分的浓度极低,排除了沥青混合料中有机化合物的硝化、磺化、胺化以及骨料中碱性活化反应的可能性。最后,本研究得出结论,由于化学性质不会影响沥青混合料的整体化学稳定性,因此所研究的RCA可作为沥青混合料中粗集料的替代品。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/60d9/7762571/467131ff94f0/materials-13-05592-g001.jpg

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