Yue Jie, Wen Guochang, Ren Guina, Tang Shaowang, Ge Bo, Zhao Limin, Shao Xin
School of Materials Science and Engineering, Liaocheng University, Liaocheng 252000, China.
School of Environmental and Material Engineering, Yantai University, Yantai 264405, China.
Langmuir. 2021 Jan 12;37(1):406-416. doi: 10.1021/acs.langmuir.0c03053. Epub 2020 Dec 27.
This research was focused on the raw material level construction of bismuth oxybromide (BiOBr) catalysis-loaded 3D cross-linked network polyurethane (PU) foam via the in situ polymerization method. After modification of superhydrophobic polydivinylbenzene nanoparticles, the PU foam possessed excellent superhydrophobic stability. The larger selective absorption oil phase capacity depended on its macroporous structure, and the existence of catalyst BiOBr (the band gap energy was about 2.57 eV) among the PU foam played a crucial role in degrading water-soluble contaminants under visible light irradiation. In this article, the photocatalytic experiment results verify that it has remarkable recycle degradation ability (the degradation efficiency can reach ∼97%) and the capture experiments indicate that the uppermost active species is h.
本研究聚焦于通过原位聚合法在溴氧化铋(BiOBr)催化负载的3D交联网络聚氨酯(PU)泡沫的原材料层面构建。经过超疏水聚二乙烯基苯纳米粒子改性后,PU泡沫具有优异的超疏水稳定性。较大的选择性吸收油相容量取决于其大孔结构,并且PU泡沫中催化剂BiOBr(带隙能量约为2.57 eV)的存在对可见光照射下水溶性污染物的降解起着关键作用。在本文中,光催化实验结果证实其具有显著的循环降解能力(降解效率可达约97%),捕获实验表明最主要的活性物种是h。