Gao Zhong-Yuan, Xiao Rong-Bo, Wang Peng, Deng Yi-Rong, Dai Wei-Jie, Liu Chu-Fan
School of Environmental Science and Engineering, Guangdong University of Technology, Guangzhou 510006, China.
Guangdong Provincial Academy of Environmental Science, Guangzhou 510045, China.
Huan Jing Ke Xue. 2021 Jan 8;42(1):343-352. doi: 10.13227/j.hjkx.202005139.
Mastering the spatial distribution of heavy metals in the soil plays an important supporting role in the scientific formulation of soil pollution risk management and control strategies. Few factors were considered and multiple collinearity between parallel variables existed,resulting in low prediction accuracy. OK (common Kriging method), NRK (regressive Kriging method based on natural factors only), and NARK (regressive Kriging based on natural-human factors)were used to simulate the spatial distribution of soil Cd by selecting 23 natural-artificial influencing factors. The prediction accuracy was evaluated based on an empirical study of the area around Shaoguan Qujiang smelter. The results showed that the above-standard rate of soil cadmium in this area reached 85.93%, and the effect on the spatial heterogeneity of soil cadmium was shown as air emissions from smelters > air emissions from steel plants > pH > organic matter > Euclidean distance to road > Euclidean distance to river. The root-mean-square error and average absolute error of NARK's prediction results for soil cadmium were 26.86% and 30.56% lower than that of the OK method, respectively. The model determination coefficient increased from 0.78 to 0.88. Compared with that of NRK, it was reduced by 24.15% and 24.23% and increased from 0.81 to 0.88. The NRK combining natural and human factors significantly improved the simulation accuracy of the spatial distribution of soil cadmium, and the addition of human factors as auxiliary variables, especially atmospheric point source pollution emissions, greatly contributed to the improvement of the model accuracy.
掌握土壤中重金属的空间分布对于科学制定土壤污染风险管理与控制策略具有重要的支撑作用。考虑的因素较少,且平行变量之间存在多重共线性,导致预测精度较低。通过选取23个自然 - 人为影响因素,采用普通克里金法(OK)、仅基于自然因素的回归克里金法(NRK)和基于自然 - 人为因素的回归克里金法(NARK)对土壤镉的空间分布进行模拟。基于韶关曲江冶炼厂周边区域的实证研究对预测精度进行评估。结果表明,该区域土壤镉超标率达85.93%,对土壤镉空间异质性的影响表现为:冶炼厂废气排放 > 钢铁厂废气排放 > pH值 > 有机质 > 到道路的欧氏距离 > 到河流的欧氏距离。NARK对土壤镉的预测结果的均方根误差和平均绝对误差分别比OK法低26.86%和30.56%。模型决定系数从0.78提高到0.88。与NRK相比,均方根误差和平均绝对误差分别降低了24.15%和24.23%,决定系数从0.81提高到0.88。结合自然和人为因素的NRK显著提高了土壤镉空间分布的模拟精度,将人为因素作为辅助变量加入,尤其是大气点源污染排放,对模型精度的提高有很大贡献。