Analytical Methods for the Assessment of Curing Kinetics of Polyurethane Binders for High-Energy Composites.

Polyurethane (PU) elastomers are largely utilized in the field of high-energy composites such as polymer-bonded explosives (PBXs) and solid rocket grains, due to their distinguished characteristics. Curing kinetics assessment is a crucial parameter to take into account to comprehend the processes to develop new high-energy composites. A comprehensive analytical characterization of curing kinetics is of fundamental importance to produce PU polymers with the most suitable and attractive properties. Moreover, to attain the optimal curing conditions, accurate analytical techniques, and strategies are essential to effectively evaluate their kinetic properties. This paper gives an overview on experimental tools, which can be used for a convenient analysis of kinetic behavior of these binders. The employment of each tool is showed and discussed by appropriate examples from the literature.