Toward a density-functional theory for the Jagla fluid.

The so-called Jagla fluid is well known to exhibit, in addition to the usual gas-liquid critical point, also a liquid-liquid critical point, as well as a density anomaly. This makes it an interesting toy model for water, for which a liquid-liquid critical point is considered to exist but so far eludes experimental verification due to crystallization occurring in the corresponding metastable, deeply supercooled state. With the Jagla fluid being understood quite well in bulk-mostly via simulation studies-the focus of the present study is to describe the spatially inhomogeneous fluid in terms of classical density-functional theory (DFT) with the aim to be able to control its phase behavior on changing the shape or the nature of the confinement of the fluid. This information might contribute to guide potential experimental tests of the liquid-liquid critical point of actual water. We first determine the bulk phase diagram for the Jagla fluid by using thermodynamical perturbation theory. In doing so we explain why the perturbation theories of Barker and Henderson as well as of Weeks, Chandler, and Anderson fail to describe the Jagla fluid. We then continue to construct a perturbative DFT based on our bulk model, which shows significant improvement over the standard mean-field DFT valid at high temperatures. But ultimately the perturbative DFT breaks down at state points close to the binodal line and at low temperatures. This prevents us from achieving the original aim to study a highly confined, inhomogeneous Jagla fluid close to its liquid-liquid binodal.