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碳量子点修饰 BiWO 可见光下高效光催化降解挥发性有机化合物。

Efficient photocatalytic degradation of volatile organic compounds over carbon quantum dots decorated BiWO under visible light.

机构信息

School of Chemistry and Chemical Engineering, Yancheng Institute of Technology, Yancheng, 224000, People's Republic of China.

Key Laboratory for Advanced Technology in Environmental Protection of Jiangsu Province, Yancheng Institute of Technology, Yancheng, 224051, People's Republic of China.

出版信息

Environ Sci Pollut Res Int. 2021 May;28(20):25949-25958. doi: 10.1007/s11356-020-12273-y. Epub 2021 Jan 22.

Abstract

A series of CQDs/BiWO (CBW) hybrid materials with different loading amounts of carbon quantum dots (CQDs) were prepared via a facile in situ hydrothermal method. As determined by multiple techniques including XRD, TEM, UV-vis, PL, TPR, and XPS, the CBW possessed expanded visible light response interval, decreased recombination rate of the photogenerated electron hole, and enhanced oxidation ability as compared with the pristine BiWO. In addition, with different loading amounts of CQDs, the optical and electronic properties of the corresponding CBW were different. These CBW materials performed superior activities to the pristine BiWO in the photodegradation of VOCs under visible light, among which the CBW-2 demonstrated the best activity of almost complete degradation within only 120 min. Moreover, the CBW-2 exhibited high stability and reusability after five cycles.

摘要

通过简便的原位水热法制备了一系列具有不同碳量子点(CQDs)负载量的 CQDs/BiWO(CBW)杂化材料。多种技术(包括 XRD、TEM、UV-vis、PL、TPR 和 XPS)的结果表明,与原始 BiWO 相比,CBW 具有扩展的可见光响应区间、降低的光生电子空穴复合率和增强的氧化能力。此外,随着 CQDs 负载量的不同,相应的 CBW 的光学和电子性质也不同。这些 CBW 材料在可见光下降解 VOCs 方面表现出优于原始 BiWO 的活性,其中 CBW-2 在仅 120 分钟内几乎完全降解,表现出最好的活性。此外,CBW-2 在经过五个循环后表现出高稳定性和可重复使用性。

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