Elowitz Mark, Sivaraman Bhalamurugan, Hendrix Amanda, Lo Jen-Iu, Chou Sheng-Lung, Cheng Bing-Ming, Sekhar B N Raja, Mason Nigel J
Department of Physical Sciences, The Open University, Milton Keynes MK7 6AA, UK.
Atomic Molecular and Optical Physics Division, Physical Research Laboratory, Ahmedabad 380 009, India.
Sci Adv. 2021 Jan 22;7(4). doi: 10.1126/sciadv.aba5749. Print 2021 Jan.
We present the first analysis of far-ultraviolet reflectance spectra of regions on Rhea's leading and trailing hemispheres collected by the Cassini Ultraviolet Imaging Spectrograph during targeted flybys. In particular, we aim to explain the unidentified broad absorption feature centred near 184 nm. We have used laboratory measurements of the UV spectroscopy of a set of candidate molecules and found a good fit to Rhea's spectra with both hydrazine monohydrate and several chlorine-containing molecules. Given the radiation-dominated chemistry on the surface of icy satellites embedded within their planets' magnetospheres, hydrazine monohydrate is argued to be the most plausible candidate for explaining the absorption feature at 184 nm. Hydrazine was also used as a propellant in Cassini's thrusters, but the thrusters were not used during icy satellite flybys and thus the signal is believed to not arise from spacecraft fuel. We discuss how hydrazine monohydrate may be chemically produced on icy surfaces.
我们展示了对土卫五(Rhea)的领先半球和落后半球区域的远紫外反射光谱的首次分析,这些光谱是由卡西尼号紫外成像光谱仪在有针对性的飞越过程中收集的。特别是,我们旨在解释以184纳米附近为中心的未识别的宽吸收特征。我们使用了一组候选分子的紫外光谱的实验室测量结果,发现一水合肼和几种含氯分子都与土卫五的光谱拟合良好。鉴于嵌入行星磁层内的冰卫星表面以辐射为主导的化学过程,一水合肼被认为是解释184纳米处吸收特征的最合理候选物。肼也被用作卡西尼号推进器的推进剂,但在飞越冰卫星期间没有使用推进器,因此该信号被认为不是来自航天器燃料。我们讨论了一水合肼如何在冰表面通过化学方式产生。