Sun Qiangqiang, Lin Shiji, Wang Dehui, Li Yong, Yang Jinlong, Deng Xu
Center for Materials Surface Science, Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China, Chengdu 610054, P. R. China.
Key Laboratory of Advanced Technologies of Materials, Ministry of Education, School of Materials Science and Engineering, Southwest Jiaotong University, Chengdu 610031, P. R. China.
iScience. 2021 Feb 20;24(3):102208. doi: 10.1016/j.isci.2021.102208. eCollection 2021 Mar 19.
In this paper, we report a finding that substrate affects the adhesion of charged super-repellent surfaces. Water droplet impacting on a super-repellent surface produces surface charge, whose expression depends on the substrate. The charged super-repellent surface is sticky to droplets for a suspended substrate made of dielectric materials, while it has low adhesion for a conducting substrate or stage attached at the bottom because of electrostatic induction. Theoretical analysis and simulation are conducted to elucidate the mechanism of substrate effect on surface adhesion. Finally, we develop a new approach to reversibly tune the adhesion of super-repellent surface by combining surface-charge-induced adhesion increase and electrostatic-induction-regulated express of net surface charge. As a proof-of-concept experiment, we demonstrate that droplet sorting and manipulations can be realized by using this controllable surface adhesion tuning approach, which has potential applications in advanced lab-on-a-drop platform.
在本文中,我们报告了一项发现,即基底会影响带电超疏水表面的附着力。水滴撞击超疏水表面会产生表面电荷,其表现取决于基底。对于由介电材料制成的悬浮基底,带电超疏水表面对水滴具有粘性,而由于静电感应,对于附着在底部的导电基底或平台,其附着力较低。进行了理论分析和模拟以阐明基底对表面附着力影响的机制。最后,我们通过结合表面电荷诱导的附着力增加和净表面电荷的静电感应调节表达,开发了一种可逆调节超疏水表面附着力的新方法。作为概念验证实验,我们证明了使用这种可控的表面附着力调节方法可以实现液滴分类和操纵,这在先进的液滴实验室平台中具有潜在应用。