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基于沉香果壳的水凝胶珠用于吸附水溶液中的阳离子和阴离子染料。

Husk of Agarwood Fruit-Based Hydrogel Beads for Adsorption of Cationic and Anionic Dyes in Aqueous Solutions.

机构信息

Department of Cosmetic Application and Management, St. Mary's Junior College of Medicine, Nursing and Management, Yilan 266, Taiwan.

Department of Chemical Engineering and Biotechnology, National Taipei University of Technology, Taipei 106, Taiwan.

出版信息

Molecules. 2021 Mar 6;26(5):1437. doi: 10.3390/molecules26051437.

Abstract

Hydrogel beads based on the husk of agarwood fruit (HAF)/sodium alginate (SA), and based on the HAF/chitosan (CS) were developed for the removal of the dyes, crystal violet (CV) and reactive blue 4 (RB4), in aqueous solutions, respectively. The effects of the initial pH (2-10) of the dye solution, the adsorbent dosage (0.5-3.5 g/L), and contact time (0-540 min) were investigated in a batch system. The dynamic adsorption behavior of CV and RB4 can be represented well by the pseudo-second-order model and pseudo-first-order model, respectively. In addition, the adsorption isotherm data can be explained by the Langmuir isotherm model. Both hydrogel beads have acceptable adsorption selectivity and reusability for the study of selective adsorption and regeneration. Based on the effectiveness, selectivity, and reusability of these hydrogel beads, they can be treated as potential adsorbents for the removal of dyes in aqueous solutions.

摘要

以琼脂果(HAF)/海藻酸钠(SA)为基础的水凝胶珠和以 HAF/壳聚糖(CS)为基础的水凝胶珠分别被开发用于去除水溶液中的染料结晶紫(CV)和活性蓝 4(RB4)。在批处理系统中研究了染料溶液初始 pH 值(2-10)、吸附剂用量(0.5-3.5 g/L)和接触时间(0-540 min)的影响。CV 和 RB4 的动态吸附行为可以分别用伪二阶模型和伪一阶模型很好地表示。此外,吸附等温线数据可以用 Langmuir 等温线模型来解释。两种水凝胶珠对选择性吸附和再生的研究均表现出良好的吸附选择性和可重复使用性。基于这些水凝胶珠的有效性、选择性和可重复使用性,它们可以被视为去除水溶液中染料的潜在吸附剂。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6504/7961690/4103941f229c/molecules-26-01437-g001.jpg

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