具有选择性晶体拓扑结构的卟啉锆金属有机框架的电解合成。
Electrolytic synthesis of porphyrinic Zr-metal-organic frameworks with selective crystal topologies.
作者信息
Okada Keito, Tanaka Yoko, Inose Tomoko, Ujii Hiroshi, Yoshikawa Hirofumi, Tanaka Daisuke
机构信息
Department of Chemistry, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda, Hyogo 669-1337, Japan.
Research Institute for Electronic Science (RIES), Hokkaido University, N20W10, Sapporo 001-0020, Japan and Institute for Integrated Cell-Material Sciences (WPI-iCeMS), Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan.
出版信息
Dalton Trans. 2021 Apr 28;50(16):5411-5415. doi: 10.1039/d1dt00491c.
The thermodynamic (PCN-222) and kinetic (PCN-224) products of porphyrinic Zr-metal-organic frameworks (MOFs) were synthesized via an anodic dissolution approach for the first time. To the best of our knowledge, this is the first report of MOF polymorphs being controlled by electrolysis. The selective formation of PCN-222 requires an amorphous component to be present on the electrode during the initial reaction process.
首次通过阳极溶解法合成了卟啉基锆金属有机框架材料（MOFs）的热力学产物（PCN - 222）和动力学产物（PCN - 224）。据我们所知，这是关于通过电解控制MOF多晶型物的首次报道。PCN - 222的选择性形成要求在初始反应过程中电极上存在无定形成分。
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