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基于细菌纤维素-钡铁氧体纳米复合材料的硬磁膜。

Hard magnetic membrane based on bacterial cellulose - Barium ferrite nanocomposites.

机构信息

Materials Science and Nanotechnology Program, Department of Physics, Faculty of Science, Khon Kaen University, Khon Kaen, 40002, Thailand.

Department of Microbiology, Faculty of Science, Khon Kaen University, Khon Kaen, 40002, Thailand.

出版信息

Carbohydr Polym. 2021 Jul 15;264:118016. doi: 10.1016/j.carbpol.2021.118016. Epub 2021 Apr 2.

Abstract

Magnetic membranes based on bacterial cellulose (BC) nanocomposites have been extensively researched. However, most magnetic nanoparticles (NPs) incorporated in the BC matrix were focused on soft magnetic phases, which limited the extensive use of magnetic BC membranes. Therefore, this work proposes a method to fabricate hard magnetic membrane based on the BC matrix and magnetically hard phase barium ferrite (BFO) NPs. The nanocomposites showed the peaked tensile strength and modulus at the low concentration of BFO whereas the magnetization increased drastically with the BFO content. They also demonstrate the high flexibility up on bending and the sensitivity to external magnetic fields. Furthermore, unlike other magnetic BC membranes, the BC/BFO nanocomposites exhibited the hard magnetic properties, i.e. they could retain their magnetic attraction after being magnetized by a permanent magnet. These properties open the possibility to employ these materials in various fields, such as information storage, anti-couterfeit or electromagnetic shieldings.

摘要

基于细菌纤维素(BC)纳米复合材料的磁性膜已经得到了广泛的研究。然而,大多数掺入 BC 基质中的磁性纳米粒子(NPs)都集中在软磁相,这限制了磁性 BC 膜的广泛应用。因此,本工作提出了一种在 BC 基质和磁性硬相钡铁氧体(BFO) NPs 上制备硬磁膜的方法。纳米复合材料在 BFO 低浓度时表现出峰值拉伸强度和模量,而磁化强度随 BFO 含量急剧增加。它们还表现出在弯曲时的高柔韧性和对外磁场的敏感性。此外,与其他磁性 BC 膜不同,BC/BFO 纳米复合材料表现出硬磁性,即它们在外加磁场下可以保持其磁性吸引力。这些特性为这些材料在信息存储、防伪或电磁屏蔽等各个领域的应用开辟了可能性。

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