Wei Yanhui, Han Wang, Li Guochang, Liang Xiaojian, Gu Zhenlu, Hu Kai
Institute of Advanced Electrical Materials, Qingdao University of Science and Technology, Qingdao 266042, China.
Polymers (Basel). 2021 Apr 22;13(9):1364. doi: 10.3390/polym13091364.
Oil-impregnated insulation paper is an important part of transformers; its performance seriously affects the life of power equipment. It is of significance to study the aging characteristics and mechanism of oil-impregnated insulation paper under thermal stress for transformer status detection and evaluation. In the work, the accelerated thermal aging was carried out at 120 °C, and DP1490, DP787, and DP311 samples were selected to represent the new, mid-aging, and late-aging status of the transformer, respectively. The space charge distribution within the specimens was measured by the pulsed electro-acoustic (PEA) method and the trap parameters were extracted based on the measurement curves. Further, the aging mechanism was studied by molecular simulation technology. A typical molecular chain defect model was constructed to study the motion of cellulose molecules under thermal stress. The experimental results show that the corresponding trap energy levels are 0.54 eV, 0.73 eV, and 0.92 eV for the new specimen, the mid-aging specimen, and the late aging specimen, respectively. The simulation results show that the trapped energy at the beginning of aging is mainly determined by the loss of H atoms. The changes in trap energy in the middle stage of aging are mainly caused by the absence of some C atoms, and the trap energy level at the end of aging is mainly caused by the breakage of chemical bonds. This study is of great significance to reveal the aging mechanism of oil-impregnated insulation paper and the modification of insulation paper.
浸油绝缘纸是变压器的重要组成部分;其性能严重影响电力设备的寿命。研究热应力作用下浸油绝缘纸的老化特性和机理对于变压器状态检测与评估具有重要意义。在这项工作中,在120℃下进行加速热老化,分别选取DP1490、DP787和DP311样本代表变压器的新、中老化和老化后期状态。通过脉冲电声(PEA)法测量试样内部的空间电荷分布,并根据测量曲线提取陷阱参数。此外,利用分子模拟技术研究老化机理。构建典型的分子链缺陷模型来研究热应力作用下纤维素分子的运动。实验结果表明,新试样、中老化试样和老化后期试样对应的陷阱能级分别为0.54eV、0.73eV和0.92eV。模拟结果表明,老化初期的陷阱能量主要由H原子的损失决定。老化中期陷阱能量的变化主要由一些C原子的缺失引起,老化末期的陷阱能级主要由化学键的断裂引起。该研究对于揭示浸油绝缘纸的老化机理和绝缘纸的改性具有重要意义。