Shenoy Aarti A, Kurtz Steven M, Gilbert Jeremy L
Department of Bioengineering, College of Engineering, Computing and Applied Science, Clemson University, Clemson, South Carolina, USA.
Clemson-MUSC Bioengineering Program, Medical University of South Carolina, Charleston, South Carolina, USA.
J Biomed Mater Res B Appl Biomater. 2021 Dec;109(12):2000-2013. doi: 10.1002/jbm.b.34854. Epub 2021 May 4.
Corrosion of modular metal-on-metal acetabular tapers in total hip arthroplasty (THA) systems is often attributed to mechanically driven processes. Recent findings suggest that mechanically assisted crevice corrosion (MACC) might not be the dominant cause of corrosion in shell-liner tapers. This study aims to document and present the corrosion modes observed in metal-metal acetabular liners. Twenty-one retrieved wrought CoCrMo liners were examined using digital optical microscopy (DOM), scanning electron microscopy (SEM) and energy dispersive x-ray spectroscopy (EDS). Corrosion-related damage was documented in nonengagement taper regions, outside of direct taper contact. Within engagement regions, nonmechanically driven corrosion features (pitting, intergranular corrosion) were observed adjacent to fretting and material transfer, which rely on mechanical contact; corrosion independent of MACC was observed even in contact regions. Corrosion types observed included intergranular corrosion (IGC), pitting attack, phase boundary dissolution, all both outside and inside of taper junctions, and MACC within contact regions of the taper. Typical fretting scars associated with MACC were mostly absent, and were not always associated with corrosion damage where present. Finally, hard phase particles (Mo-Si-O) released from the wrought CoCrMo microstructure had redeposited within regions with material loss. Acetabular taper corrosion modes differ significantly from those in head-neck tapers and are dominated by electrochemically driven processes, not mechanical processes, as indicated by corrosion in noncontact regions. With greater prevalence of dual mobility hip implants, acetabular taper corrosion processes must be understood in order to limit their impact on device performance.
全髋关节置换术(THA)系统中模块化金属对金属髋臼锥度的腐蚀通常归因于机械驱动过程。最近的研究结果表明,机械辅助缝隙腐蚀(MACC)可能不是髋臼杯衬垫锥度腐蚀的主要原因。本研究旨在记录并呈现金属对金属髋臼杯衬垫中观察到的腐蚀模式。使用数字光学显微镜(DOM)、扫描电子显微镜(SEM)和能量色散X射线光谱仪(EDS)对21个回收的锻造钴铬钼衬垫进行了检查。在直接锥度接触区域之外的非啮合锥度区域记录了与腐蚀相关的损伤。在啮合区域内,在依赖机械接触的微动和材料转移附近观察到非机械驱动的腐蚀特征(点蚀、晶间腐蚀);即使在接触区域也观察到与MACC无关的腐蚀。观察到的腐蚀类型包括晶间腐蚀(IGC)、点蚀、相界溶解,在锥度连接处的内外均有,以及在锥度接触区域内的MACC。与MACC相关的典型微动疤痕大多不存在,并且在存在时也并不总是与腐蚀损伤相关。最后,从锻造钴铬钼微观结构中释放出的硬质相颗粒(Mo-Si-O)在材料损失区域内重新沉积。髋臼锥度腐蚀模式与头颈锥度的腐蚀模式有显著差异,并且如非接触区域的腐蚀所示,其主要由电化学驱动过程而非机械过程主导。随着双动髋关节植入物的普及,必须了解髋臼锥度腐蚀过程,以限制其对器械性能的影响。