Institute of Materials Science and Technology, Analytical & Testing Center, Sichuan University, Chengdu 610065, China.
College of Chemical Engineering and Materials Science, Tianjin University of Science and Technology, Tianjin 300457, China.
J Hazard Mater. 2021 Sep 5;417:126033. doi: 10.1016/j.jhazmat.2021.126033. Epub 2021 May 8.
In this study, a novel, oxidized poly (arylene sulfide sulfone) (O-PASS) nanofibrous membrane filter was successfully fabricated for the effective removal of particulate matter. PASS was electrospun into a nanofibrous membrane with an average nanofiber diameter of 0.31 µm and basis weight of 3 g/m. These specifications were chosen as they showed high particulate matter removal efficiency (99.98%), low pressure drop (68 Pa), and high quality factor Q (0.125 Pa). In addition, the filtration mechanism of the PASS nanofibrous membrane was intuitively revealed by simulating the intercepted particular distributions and motion paths of particles. After a simple oxidation treatment, the O-PASS nanofibrous membrane was successfully built up. The microstructure and morphology showed little change compared with the PASS nanofiber, but the oxidation treatment significantly improved the mechanical properties of the membrane from 1.51 MPa to 4.92 MPa. More importantly, the O-PASS nanofibrous membrane still exhibited high removal efficiency after high temperature, acid, alkali, or organic solvent treatments. Overall, O-PASS nanofibrous membranes are promising high-performance filter materials with high temperature and corrosion resistance.
在这项研究中,成功制备了一种新型的氧化聚(芳基硫醚砜)(O-PASS)纳米纤维膜过滤器,用于有效去除颗粒物。PASS 通过静电纺丝制成纳米纤维膜,平均纳米纤维直径为 0.31 µm,基重为 3 g/m。之所以选择这些规格,是因为它们表现出了高颗粒物去除效率(99.98%)、低压降(68 Pa)和高品质因数 Q(0.125 Pa)。此外,通过模拟截留颗粒物的分布和运动轨迹,直观地揭示了 PASS 纳米纤维膜的过滤机制。经过简单的氧化处理,成功制备了 O-PASS 纳米纤维膜。与 PASS 纳米纤维相比,其微观结构和形貌几乎没有变化,但氧化处理显著提高了膜的机械性能,从 1.51 MPa 提高到 4.92 MPa。更重要的是,O-PASS 纳米纤维膜在经过高温、酸碱或有机溶剂处理后仍保持高去除效率。总体而言,O-PASS 纳米纤维膜是一种具有耐高温和耐腐蚀性的高性能过滤材料。