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运行参数对130t/h循环流化床燃烧系统氯释放及污染物排放特性的影响

Influence of Operating Parameters on Chlorine Release and Pollutant Emission Characteristics of a 130 t/h BCFB Combustion System.

作者信息

Liu Yaya, Liu Shanjian, Li Yingjie, Li Yongjun, He Jianjie

机构信息

School of Agricultural Engineering and Food Science, Shandong University of Technology, Zibo 255049, China.

出版信息

ACS Omega. 2021 May 6;6(19):12530-12540. doi: 10.1021/acsomega.1c00270. eCollection 2021 May 18.

Abstract

A 130 t/h biomass circulating fluidized bed (BCFB) boiler combustion system model, considering the chloride release and pollutant emissions during the biomass combustion, was established using the Modelica language. The effects of the biomass feed amount, limestone amount, excess air coefficients, and different ratios of primary and secondary air on the boiler furnace temperature and flue gas composition (O, CO, SO, HCl, and KCl) were investigated. Upon the biomass feed amount step change, the variation ranges of NO and KCl concentrations were very large, which were 18.58 and 21.16% of the before step value, respectively. The step change of the limestone input had little effect on b ed temperature in the dense phase zone, but it could obviously reduce the SO concentration. The concentration of SO in flue gas decreased by 22.56% when the limestone input increased by 50%. The removal rate of SO gradually decreased with the increase of the limestone amount. The SO desulfurization rate decreased by 68.30% when the amount of limestone increased from 0.0275 to 0.0825 kg/s. More NO would be generated and KCl concentration would be significantly reduced with the increase of the excess air coefficient. When the ratio of primary and secondary air was 4:6, the NO concentration in flue gas was lower than 86.06 mg/Nm.

摘要

利用Modelica语言建立了一个130 t/h生物质循环流化床(BCFB)锅炉燃烧系统模型,该模型考虑了生物质燃烧过程中的氯释放和污染物排放。研究了生物质进料量、石灰石量、过量空气系数以及一次风和二次风的不同比例对锅炉炉膛温度和烟气成分(O、CO、SO、HCl和KCl)的影响。在生物质进料量发生阶跃变化时,NO和KCl浓度的变化范围非常大,分别为阶跃前值的18.58%和21.16%。石灰石输入量的阶跃变化对密相区床温影响较小,但能明显降低SO浓度。当石灰石输入量增加50%时,烟气中SO浓度降低了22.56%。SO的去除率随着石灰石量的增加而逐渐降低。当石灰石量从0.0275 kg/s增加到0.0825 kg/s时,SO脱硫率降低了68.30%。随着过量空气系数的增加,会产生更多的NO,KCl浓度会显著降低。当一次风和二次风的比例为4:6时,烟气中NO浓度低于86.06 mg/Nm³。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/37c7/8154120/4f473963e522/ao1c00270_0002.jpg

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