College of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044, China.
College of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044, China.
J Colloid Interface Sci. 2021 Dec 15;604:1-14. doi: 10.1016/j.jcis.2021.07.034. Epub 2021 Jul 8.
In this work, novel N-doped carbon dots (N-CDs) were synthesized from citric acid and l-serine. The results of fourier transform infrared (FT-IR) and X-ray photoelectron spectroscopy (XPS) show that there are many unsaturated bonds and polar groups in the N-CDs. The inhibition performance of the concerned zero-dimensional nanomaterial for copper was investigated by electrochemical, combining FT-IR, XPS and Raman to investigate the corrosion products. Results indicate that the N-CDs were found to be effective inhibitor with the suppression efficiency as high as 98.5% means after immersed for 24 h, and they interacted with copper substrate by chemical & physical adsorption. Moreover, the related anticorrosion mechanism was explored and elucidated in detail. The purpose of this work is to explore eco-friendly and efficient corrosion inhibitor materials for metal protection.
在这项工作中,我们从柠檬酸和 l-丝氨酸合成了新型氮掺杂碳点(N-CDs)。傅里叶变换红外(FT-IR)和 X 射线光电子能谱(XPS)的结果表明,N-CDs 中存在许多不饱和键和极性基团。通过电化学方法,结合 FT-IR、XPS 和 Raman 研究了有关零维纳米材料对铜的抑制性能及其腐蚀产物。结果表明,N-CDs 是一种有效的抑制剂,在浸泡 24 小时后,抑制效率高达 98.5%,它们通过化学和物理吸附与铜基体相互作用。此外,还详细探讨和阐明了相关的防腐机理。本工作旨在探索用于金属保护的环保、高效的腐蚀抑制剂材料。