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氨基酸功能化碳点的溶剂热合成及其作为一种环保型铜缓蚀剂在硫酸溶液中的应用。

Solvothermal synthesis of functionalized carbon dots from amino acid as an eco-friendly corrosion inhibitor for copper in sulfuric acid solution.

机构信息

College of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044, China.

College of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044, China.

出版信息

J Colloid Interface Sci. 2021 Dec 15;604:1-14. doi: 10.1016/j.jcis.2021.07.034. Epub 2021 Jul 8.

Abstract

In this work, novel N-doped carbon dots (N-CDs) were synthesized from citric acid and l-serine. The results of fourier transform infrared (FT-IR) and X-ray photoelectron spectroscopy (XPS) show that there are many unsaturated bonds and polar groups in the N-CDs. The inhibition performance of the concerned zero-dimensional nanomaterial for copper was investigated by electrochemical, combining FT-IR, XPS and Raman to investigate the corrosion products. Results indicate that the N-CDs were found to be effective inhibitor with the suppression efficiency as high as 98.5% means after immersed for 24 h, and they interacted with copper substrate by chemical & physical adsorption. Moreover, the related anticorrosion mechanism was explored and elucidated in detail. The purpose of this work is to explore eco-friendly and efficient corrosion inhibitor materials for metal protection.

摘要

在这项工作中,我们从柠檬酸和 l-丝氨酸合成了新型氮掺杂碳点(N-CDs)。傅里叶变换红外(FT-IR)和 X 射线光电子能谱(XPS)的结果表明,N-CDs 中存在许多不饱和键和极性基团。通过电化学方法,结合 FT-IR、XPS 和 Raman 研究了有关零维纳米材料对铜的抑制性能及其腐蚀产物。结果表明,N-CDs 是一种有效的抑制剂,在浸泡 24 小时后,抑制效率高达 98.5%,它们通过化学和物理吸附与铜基体相互作用。此外,还详细探讨和阐明了相关的防腐机理。本工作旨在探索用于金属保护的环保、高效的腐蚀抑制剂材料。

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