Department of Chemistry, National Institute of Technology, Silchar, Assam, 788010, India.
Environ Sci Pollut Res Int. 2021 Sep;28(34):46910-46933. doi: 10.1007/s11356-021-15251-0. Epub 2021 Jul 14.
Fly ash is readily available and cheaply generated as 47a by-product of the combustion of organic matter. A tremendous amount of fly ash is generated worldwide, and its disposal has imposed 47a severe environmental concern. Its good adsorption capacities attracted several researchers to study the use of fly ash as 47a support for photocatalysts for the degradation of contaminants from wastewater. Undoubtedly the photocatalysts supported on fly ash have represented excellent degradation efficiencies due to the synergistic effect of adsorption and photocatalytic capacity. The utilization of fly ash as 47a precursor has solved the problem of disposal and added value to the waste by-product. Various preparation techniques for fly ash-based nanocomposites such as the sol-gel method, hydrothermal method, solvothermal method, precipitation and co-precipitation, modified metalorganic decomposition, electrospinning, incipient impregnation, and wet chemical synthesis, along with 47a brief study of their characterization using scanning electron microscopy, X-ray diffraction technique and Fourier transform infrared (FTIR) spectroscopy, and the mechanism of photodegradation of dyes have been discussed in this paper. The literature shows that SiO, TiO, and AlO present in fly ash play an essential role in the photodegradation of dyes. Factors affecting the degradation of dyes, their kinetic studies, and methods to enhance photodegradation efficiency have also been discussed.
粉煤灰是一种极易获得且廉价的物质,是有机物燃烧的 47a 副产品。全球产生了大量的粉煤灰,其处理给环境带来了严重的关注。它良好的吸附能力吸引了许多研究人员研究将粉煤灰用作光催化剂的载体,以降解废水中的污染物。由于吸附和光催化能力的协同作用,负载在粉煤灰上的光催化剂无疑表现出了优异的降解效率。将粉煤灰用作 47a 前体不仅解决了废物处理问题,还为废物副产物增加了附加值。本文讨论了各种制备粉煤灰基纳米复合材料的方法,如溶胶-凝胶法、水热法、溶剂热法、沉淀和共沉淀法、改良的金属有机分解法、静电纺丝法、初始浸渍法和湿化学合成法,并简要研究了它们的特性,包括扫描电子显微镜、X 射线衍射技术和傅里叶变换红外(FTIR)光谱,以及染料光降解的机制。文献表明,粉煤灰中的 SiO、TiO 和 AlO 在染料的光降解中起着重要作用。本文还讨论了影响染料降解的因素、动力学研究以及提高光降解效率的方法。